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. 2022 May 10;144(20):8951–8960. doi: 10.1021/jacs.1c10584

Table 1. Fitting Form and Structure Factors for SAXS of Fully Oxidized {P2W18} Solutionsb.

formula conc. (mMolar) cluster radius (Å) Etaa (Å) Phib
Li6[P2W18O62] 50 5.7 24 0.7
50-Li-{P2W18}        
Na6[P2W18O62] 50 5.7 23 0.5
50-Na-{P2W18}        
K6[P2W18O62] 60 5.7 22 0.6
60-K-{P2W18}        
a

Half of the center-to-center distance of clusters. A unit-less term that describes the “pack” of the clusters, or how many nearest neighbors surround each cluster (larger number indicates more “nearest neighbor” clusters).

b

See Figures S4-SAXS, S5-SAXS, and S6-SAXS for the data fits.