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. 2021 Jul 14;9(29):9541–9562. doi: 10.1021/acssuschemeng.1c02558

Table 2. ASTM Convention for a PU Coating Classification, Its Technology Definition, and Typical Applications, Adapted from the Work of Sonnenschein19.

ASTM convention technology applications
type I cured by oxidative cross-linking of unsaturated polyester groups and solvent evaporation architectural floors and maintenance, topcoats
type II contains free isocyanates, reacts with moisture; various blocking techniques to preserve isocyanate reactivity for extended shelf life leathers, concretes, maintenance
type III one-part heat cure; uses blocked isocyanates that are liberated upon heating to react with isocyanate-reactive components in the formulation coils and electric wires
type IV two-part solvent-borne; one part is the prepolymer polyisocyanate, and the second one contains all other components (polyol(s), catalyst, solvents, pigments, and other additives); ambient or heat curing plastics, wood furniture, marine exteriors
type V two-part high solid (>50%) coatings; one part is a prepolymer and the second one is a polyol leathers, wood, automotive clear coats, refinishes, aircraft, bus, trucks, industrial structure maintenance coatings
type VI one-component nonreactive low solid (<20%) solvent-borne; high gloss film forms upon solvent evaporation textiles
powder coatings one-part reactive system using caprolactam or 1,2,4 triazole blocked aliphatic isocyanates automotive exterior panels and parts, wires, electrical transmission equipment, surfaces, metal surfaces, outdoor lawn furniture
radiation high solid coatings, rapid cure, high gloss, not practical for home use or complex shapes; made by reacting isocyanate-capped prepolymer with hydroxyl functionalized acrylate or methacrylate manufactured wood flooring, cabinets, metal surfaces, plastics
waterborne broadly applied to one- and two-part systems using aliphatic or aromatic isocyanates; reduces VOC exposure, can be used in hybrid technologies wood coatings, decorative coatings, artificial leathers, textiles, plastics, inks, architectural, automotive