TABLE 1.
Low- and high-energy channel ions queried in the UHPLC-QTOF-MS data files for each common benzodiazepine [M + H]+: protonated molecule.
| Low-energy channel ions | |
| m0 | [M + H]+ |
| m1 | Isotope with one 13C |
| m2 | If Br in molecular formula: isotope with one 81Br |
| If Cl(s) and not Br in molecular formula: isotope with one 37Cl | |
| If halogens not in molecular formula: isotope with two 13C | |
| High-energy channel | |
| f0 | [M + H]+ |
| f1 | First diagnostic fragment ion |
| f2 | Second diagnostic fragment ion |
| f3 | Third diagnostic fragment ion |
| f4 | Fourth diagnostic fragment ion |