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. 2022 May 19;10:868532. doi: 10.3389/fchem.2022.868532

TABLE 1.

Low- and high-energy channel ions queried in the UHPLC-QTOF-MS data files for each common benzodiazepine [M + H]+: protonated molecule.

Low-energy channel ions
 m0 [M + H]+
 m1 Isotope with one 13C
 m2 If Br in molecular formula: isotope with one 81Br
If Cl(s) and not Br in molecular formula: isotope with one 37Cl
If halogens not in molecular formula: isotope with two 13C
High-energy channel
 f0 [M + H]+
 f1 First diagnostic fragment ion
 f2 Second diagnostic fragment ion
 f3 Third diagnostic fragment ion
 f4 Fourth diagnostic fragment ion