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. Author manuscript; available in PMC: 2022 Jun 8.
Published in final edited form as: Chem Rev. 2021 Dec 20;122(1):1–49. doi: 10.1021/acs.chemrev.1c00521

Figure 9.

Figure 9.

(A) Scheme for estimating a Mo-diazenido N–H BDFE (HITP = 3,5-(2,4,6-iPr3C6H2)2-C6H3); the BDFEN–H has been edited to reflect our updated CG value in THF. Reprinted (adapted) with permission from ref 192. Copyright 2017 Springer Nature. (B) Suggested generation and disproportionation of P3SiFe–N═NH to P3SiFe–N2 and P3SiFe═N–NH2; the cationic hydrazido complex is drawn at the right, showing the structure of the P3Si ligand. Reprinted with permission from ref 191. Copyright 2017 American Chemical Society. (C) Scheme for theN–H BDFEs in (dppe)2(L)Mo(═NN(Cy)H)n+. Reprinted with permission from ref 188. Copyright 2016 Royal Chemical Society.