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. 2022 May 23;7(22):18382–18408. doi: 10.1021/acsomega.2c00669

Table 7. Summary of All Experimentally Investigated Core Levels on XPS, Their Content, And Theoretically Derived, Ideological Formulae for BCW (Normalized to W) and CCWO (Normalized to Ce) Based on Given Total Atomic Ratios.

Material Core level s–o split Position (eV) fwhm(eV) Total atom (%) Ratio
BCW W 4f 7/2 33.4, 34.4 1.65, 0.86 8.96 1
5/2 35.4, 36.4 1.13, 0.88
O 1s   529.9, 531.8 1.78, 2.68 61.01 6.81
Ba 3d 5/2 780.4, 783.2 2.21, 1.47 19.46 2.17
3/2 793.2, 795.5 1.16, 1.88
Ce 3d 5/2 880.6, 883.1, 886.2, 889.6, 896.0 1.08, 2.20, 2.56, 3.64, 1.03 10.57 1.18
3/2 898.3, 900.2, 903.0, 905.2, 917.3 1.91, 2.63, 2.31, 3.09, 2.51
CCWO W 4f 7/2 34.6, 36.4 1.27, 1.96 9.56 1.92
5/2 36.5, 38.1 1.39, 1.76
Ca 2p 3/2 345.8, 347.2 1.23, 2.00 15.56 3.12
1/2 349.2, 350.7 1.03, 1.94
O 1s   531.4, 532.6 1.59, 2.60 64.92 13.04
Ce 3d 5/2 880.5, 883.4, 885.8, 889.0, 896.8 3.53, 3.66, 2.26, 2.85, 3.17 9.96 2
3/2 899.8, 902.3, 904.4, 907.6, 915.4 3.22, 3.73, 3.02, 3.07, 2.84