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. 2021 Feb 5;60(4):2783–2796. doi: 10.1021/acs.inorgchem.0c03680

Table 4. Mixed-Valence and IVCT Parameters.

complex νmax/cm–1a Δν1/2/cm–1a Δν1/20/cm–1a Γb
[7]+ 9676 2287 4728 0.51
[7]3+ 11088 3467 5061 0.31
[8]+ 6307 1427 3817 0.63
[8]2+ 5338 742 3511 0.78
[8]3+ 6481 1045 3869 0.72
[11]+ 11131 2001 5071 0.61
a

From Gaussian fit of ε/ν versus ν.

b

Parameters calculated using eq 2.