Substrate scope of thioamide 1a.
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Reaction conditions: a mixture of 1 (0.3 mmol) and 15 mg of chlorophyll powder (5 mol%) in 3 mL MeCN was stirred and irradiated with 455 nm blue light-emitting diodes (LED) at r.t. open to air.
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Reaction conditions: a mixture of 1 (0.3 mmol) and 15 mg of chlorophyll powder (5 mol%) in 3 mL MeCN was stirred and irradiated with 455 nm blue light-emitting diodes (LED) at r.t. open to air.