Table 5.

Oxidation kinetics parameters of analysed oils.

Oil	Z	Kinetic Parameter
		k [h−1]							Ea [kJ/mol]	ΔH [kJ/mol]	ΔS [J/mol K]
		80 °C	90 °C	100 °C	105 °C	110 °C	115 °C	120 °C
PO	2.07 × 1010	-	-	0.11	0.16	0.23	0.31	0.43	80.40	77.22	−126.02
HO	7.16 × 109	0.29	0.40	0.55	0.75	1.01	-	-	72.23	69.12	−132.93
LO	6.55 × 1011	0.39	0.57	0.83	1.19	1.70	-	-	84.99	81.87	−95.06
CO	1.18 × 1010	-	-	0.53	0.72	0.98	1.32	1.77	73.94	70.76	−130.56
RO	7.99 × 109	-	-	0.17	0.24	0.32	0.44	0.59	76.23	73.05	−133.82
BCO	1.65 × 1013	-	-	0.09	0.13	0.20	0.31	0.46	102.02	98.84	−70.33
MTO	1.04 × 1011	-	-	0.24	0.34	0.48	0.68	0.94	83.11	79.93	−119.71
EPO	4.26 × 1010	-	-	0.38	0.53	0.74	1.01	1.38	78.94	75.76	−123.41
M1	4.61 × 1010	0.35	0.49	0.69	0.96	1.32	-	-	77.32	74.20	−123.97
M2	1.36 × 1011	0.37	0.53	0.76	1.06	1.48	-	-	80.39	77.28	−104.30
M3	5.83 × 109	-	-	0.18	0.25	0.34	0.47	0.62	75.03	71.84	−119.24

Ea—activation energy; ΔH—entalphy; ΔS—entropy; k—reaction rate coefficient; Z—pre-exponential factor; PO—pumpkin oil; HO—hemp oil; LO—linseed oil; CO—camelina oil; RO—rapeseed oil; BCO—black cumin oil; MTO—milk thistle oil; EPO—evening primrose oil; M1—70% LO, 27% MTO, 3% EPO; M2—80% RO, 17% LO, 3% EPO; M3—91% LO, 5% EPO, 4% PO.