Table 1.
The summary of the properties of nanomaterials as adsorbents in combination with other technologies.
Sample | Target Analyte | Adsorbent | Pretreatment Method | Detection | LOD (µg/mL) |
Recovery (%) |
Ref. |
---|---|---|---|---|---|---|---|
Crude oil | As(III) As(V) |
C60-SESMP-Fe3O4 | MSPE | ICP-OES | 0.047–0.032 | 96.5–98.0 | [48] |
Wild rice |
Pb (II) | ox-MWCNTs/ batophenanth |
DMSPE | FAAS | 0.25 | 93.8 | [60] |
Sewage water | U(VI) | Br-PADAP/MWCNT | MSPE | ICP-AES | 0.14 | 99.7 | [61] |
Cosmetics | Parabens | MoS2/GO | DSPE | UPLC-PDA | 0.40~2.3 | 91.3–124 | [71] |
Sewage water | PCAs | UIO-66-NMe3+MMM | DME | UHPLC-MS/MS | 0.030–0.59 | 80.1–117 | [88] |
Tap water | Pd(II) | UIO-66-Pyta | SPE | ICP-AES | 1.9 | 99.0 | [89] |
Duck, Grass Carp | TCs | PAN@COF-SCU1 | PT-SPE | HPLC | 0.60–3.0 | 84.0–117 | [94] |
Human Plasma prior | Anesthetics | PS-IL-COFS | OSCE | LC-MS/MS | 0.016–0.18 | 82.5–115 | [95] |
Rice, apples, green groceries |
PCAs | TAPT-DHTA-COF | SPE | LC-MS/MS | 0.0070–0.030 | 81.2–107 | [96] |
River water | OPPS | PAN/Ni-MOF | HS-SPME | CD-IMS | 0.20–0.30 | 87.0–98.0 | [90] |
River water | FQS | IL-COOH/Fe3O4@Zr-MOF | MSPE | HPLC-DAD | <0.020 | 90.0–110 | [111] |
Meat, vegetables | Toxic alkaloids | PAMAM@Mag-CNTs | DPT-MSPE | UFLC-MS/MS | 0.011~0.329 | 83.4–125 | [113] |
Urine | Psychoactive drugs | GO-Fe3O4 | MSPE | UHPLC-MS/MS | 0.020–0.20 | 80.4–105 | [114] |