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. 2022 Jun 13;13:3376. doi: 10.1038/s41467-022-30735-4

Fig. 2. Establishing optimal reaction conditions for the catalytic conversion of 1 G to PC.

Fig. 2

Standard reaction conditions unless otherwise specified: 1 G (1.1 mmol, 0.200 g), 1 g wet Raney Ni, 100 °C, 2 h, 10 bar H2, 15 mL solvent, 10 mg dodecane. Screening of A commercially available heterogeneous metal catalysts; B different gas phases: air, N2, and H2; C various solvents; D reaction temperature; A–D For numerical values see Supplementary Supplementary Table S1–S4; Conversion and yield values were determined by GC-FID using calibration curves and internal standard; E Proposed reaction network and calculated apparent rate constants from data fitting, utilizing the DynaFit software (kapp in 10−3 min−1); F Fitting of the experimental data for catalytic conversion of 1 G, 1, 1H, and PC over wet Raney Ni catalyst. Reaction conditions: 1.1 mmol substrates, 0.500 g wet Raney Ni, 100 °C, 20 bar H2, 20 mL isopropanol, 20 mg dodecane as internal standard. Data were presented in detail in Supplementary Tables S6–S8.