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. 2022 Jun 20;13:3524. doi: 10.1038/s41467-022-31234-2

Fig. 1. Enantioselective approaches to access chiral bis(boryl)alkanes.

Fig. 1

A Enantioselective hydroboration of alkenylBdan to chiral 1,1-diborons. B Asymmetric hydrogenation of 1,1-diboryl alkenes to chiral 1,1-diboryl alkanes. C Enantioselective Co-catalyzed hydrosilylation and hydroboration of alkynes to chiral 1,1-silyboronates (our previous work). D Our strategy for enantioselective copper-catalyzed double hydroboration of alkynes to chiral 1,1-diborons (this work).