Table 1.

Thermodynamic parameters of the supramolecular homopolymerization of 1–3 obtained by temperature-dependent spectroscopic data^a.

Monomer	ΔHe (kJ mol−1)	ΔHn (kJ mol−1)	ΔS (J mol−1 K−1)	ΔGeb (kJ mol−1)	σb
1	−74.5	−41.2	−160	−26.7	1.5 × 10−6
2	−74.6	−44.1	−162	−26.3	4.6 × 10−6
3	−95.0	−81.5	−222	−29.0	4.3 × 10−3

^aThe thermodynamic parameters were obtained by analyzing data acquired from CD spectroscopic experiments for 1–2 and absorption spectroscopic experiments for 3.

^bChanges in Gibbs free energy of elongation (ΔG_e) and the cooperativity factor (σ) are reported for a temperature of 298 K.