Table 2.

Calculated ΔH, ΔG^≠ (kcal mol⁻¹), tunnelling corrections (κ) and k_Eck (M⁻¹ s ⁻¹), branching ratios (Γ, %) at 298.15 K for the HOO^• + 7OGT reaction.

reactions	ΔH	ΔG≠	κ	kEck	Γ
7OGT − C2 − H + HOO•	7.3	16.6	36.4	1.51 × 102	0.0
7OGT − O5 − H + HOO•	3.7	13.5	23.1	1.93 × 104	0.0
7OGT − O12 − H + HOO•	3.9	13.4	46.8	4.23 × 104	0.0
7OGT − O13 − H + HOO•	4.3	14.6	53.3	6.63 × 103	0.0
7OGT − O3′ − H + HOO•	2.6	12.3	19.3	1.13 × 105	0.0
7OGT − O4′ − H + HOO•	−2.0	7.4	19.6	4.58 × 108	100.0
koverall	4.58 × 108