Table 3.

ΔG^≠ (kcal mol⁻¹), λ, κ, k_app, k_f, k_overall (M⁻¹ s⁻¹) and Γ (%) of the 7OGT + HOO^• reaction in the physiological media.

mechanisms		pentyl ethanoate				water
		ΔG≠	κ	kapp	Γ	ΔG≠	κ	kapp	f	kbf	Γ
SET	H2A	113.2	19.7	7.10 × 10−71	0.0	31.1	19.0a	9.60 × 10−11	0.207	1.99 × 10−11	0.0
	HA−					9.0	17.1a	1.40 × 106	0.702	9.83 × 105	0.4
	A2−					4.3	18.2a	2.90 × 109	0.091	2.64 × 108	99.6
FHT	H2A	14.2	59.9	1.40 × 104	100.0	15.8	587.0	9.60 × 103	0.207	1.99 × 103	0.0
koverall				1.40 × 104						2.65 × 108

^aλ.

^bk_f = f.k_app; k_overall = ∑k_f(_kapp).