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. 2022 Jun 22;14(2):195–207. doi: 10.1134/S207005042202009X

Table 1.  .

Solid catalysts and organic solvents in synthesis of APA from sylvane

Catalyst Conditions Solvent for sylvane and water Yield of APA, wt % Ref.
Pd black 50°C 53 [17]
Pd/С in hydrochloric acid 40–65°C, 3–7 atm 75 [32, 33]
Pd/C in hydrochloric acid 25°C, 1.7–2.5 atm, flow reactor Acetone 65–75 [14, 34–36]
Pd/C in hydrochloric acid 25–30 °C, 2.8 atm, рН 6–7 85 [37]
Pd/C 25°C, 1.7–2.5 atm, citrate buffer system 73 [38]
Pd/C 20°C, 0.05–15% of thiazole 61 [39]
Pd/KU-2 50–60°С, 0.6 MPa Acetone 58 [40]
Pd/Al2O3(IK-7-1) 50–60°С, 0.6 MPa Acetone 63 [40]
Pd/Al2O3(IK-7-1) 60–70°С, 0.2–0.6 MPa, flow reactor Isopropanol 70 [27]
Ni–Cr, Ni–Al, Ni–zeolite Formic acid, 150°С, 75 atm, flow reactor Dioxane 30–40 [14]
Ni–kieselgur Formic acid, 160°C, 11 MPa Methanol 34 [25]