Table 1. .
Solid catalysts and organic solvents in synthesis of APA from sylvane
| Catalyst | Conditions | Solvent for sylvane and water | Yield of APA, wt % | Ref. |
|---|---|---|---|---|
| Pd black | 50°C | — | 53 | [17] |
| Pd/С in hydrochloric acid | 40–65°C, 3–7 atm | — | 75 | [32, 33] |
| Pd/C in hydrochloric acid | 25°C, 1.7–2.5 atm, flow reactor | Acetone | 65–75 | [14, 34–36] |
| Pd/C in hydrochloric acid | 25–30 °C, 2.8 atm, рН 6–7 | — | 85 | [37] |
| Pd/C | 25°C, 1.7–2.5 atm, citrate buffer system | — | 73 | [38] |
| Pd/C | 20°C, 0.05–15% of thiazole | — | 61 | [39] |
| Pd/KU-2 | 50–60°С, 0.6 MPa | Acetone | 58 | [40] |
| Pd/Al2O3(IK-7-1) | 50–60°С, 0.6 MPa | Acetone | 63 | [40] |
| Pd/Al2O3(IK-7-1) | 60–70°С, 0.2–0.6 MPa, flow reactor | Isopropanol | 70 | [27] |
| Ni–Cr, Ni–Al, Ni–zeolite | Formic acid, 150°С, 75 atm, flow reactor | Dioxane | 30–40 | [14] |
| Ni–kieselgur | Formic acid, 160°C, 11 MPa | Methanol | 34 | [25] |