Table 1. The CO resistance of Pt-based catalysts.
Conditions: 0.1 mmol of substrate, 3 ml of DMF, and 2 mg of catalyst. Gas: H2 or 0.1%-CO/H2. Reaction time: 1.5 hours (entries 1 to 6, 9 to 16, and 18 to 23) and 2 hours (entries 7, 8, and 17).
Entry | Catalyst | Product in Fig. 5 | Gas | Con./Sel.% |
1 | Pt/C | 2a | H2 | 99.9/69.5 |
2 | H2/CO | 0/0 | ||
3 | Twinned Pt2Mo/C | 2a | H2 | 99.9/95.7 |
4 | H2/CO | 99.9/99.9 | ||
5 | 2b | H2 | 99.9/96.4 | |
6 | H2/CO | 99.9/96.7 | ||
7 | 2c | H2 | 99.9/99.9 | |
8 | H2/CO | 99.9/99.9 | ||
9 | 2d | H2 | 99.9/99.9 | |
10 | H2/CO | 99.9/99.9 | ||
11 | 2e | H2 | 99.9/99.9 | |
12 | H2/CO | 99.9/99.9 | ||
13 | 2f | H2 | 99.9/99.9 | |
14 | H2/CO | 99.9/99.9 | ||
15 | Twinned Pt2W/C | 2a | H2/CO | 99.9/99.9 |
16 | 2b | H2/CO | 99.9/94.4 | |
17 | 2c | H2/CO | 95.7/99.9 | |
18 | 2d | H2/CO | 99.9/99.9 | |
19 | 2e | H2/CO | 99.9/99.9 | |
20 | 2f | H2/CO | 99.9/99.9 | |
21 | Untwinned Pt2Mo/C | 2a | H2 | 99.9/50.4 |
22 | H2/CO | 5.2/78.2 | ||
23 | Untwinned Pt2Mo/Al2O3 | 2a | H2/CO | 68.2/18.3 |
24 | Untwinned Pt2Mo/MgO | H2/CO | 17.8/17.6 |