Table 1.
Information of the 352 pesticides detected in chrysanthemum flower samples by GC-Orbitrap-MS screening.
| Pesticides | CAS | Molecular formula | Retention time (min) | Quantitative ion (m/z) | Qualitative ion (m/z) | |
|---|---|---|---|---|---|---|
| 1 | 2 | |||||
| Clopyralid | 1702-17-6 | C6H3Cl2NO2 | 6.38 | 146.96 | 76.02 | 111.99 |
| Dichlorvos | 62-73-7 | C4H7O4PCl2 | 7.99 | 184.98 | 186.97 | 144.98 |
| Methamidophos | 10265-92-6 | C2H8NO2PS | 8.02 | 141.00 | 112.01585 | 125.98 |
| Thiofanox | 39196-18-4 | C9H18N2O2S | 8.20 | 115.10 | 161.09 | 83.07 |
| Allidochlor | 93-71-0 | C8H12NOCl | 8.27 | 138.09 | 132.02 | 96.08 |
| Dichlobenil | 1194-65-6 | C7H3Cl2N | 8.68 | 170.96 | 100.02 | 172.96 |
| EPTC | 759-94-4 | C9H19NOS | 8.71 | 128.11 | 132.08 | 160.08 |
| Dichlormid | 37764-25-3 | C8H11Cl2NO | 8.72 | 172.05 | 108.08 | 165.98 |
| 2,4,6-Trichlorophenol | 88-06-2 | C6H3OCl3 | 8.73 | 195.92 | 199.92 | 197.92 |
| 3,5-Dichloroaniline | 626-43-7 | C6H5Cl2N | 9.05 | 160.98 | 162.98 | 126.01 |
| O-phthalimide | 85-41-6 | C8H5NO2 | 9.15 | 147.03 | 103.04 | 104.03 |
| Mevinphos | 7786-34-7 | C7H13O6P | 9.18 | 192.02 | 164.02 | 127.01 |
| Acephate | 30560-19-1 | C4H10NO3PS | 9.25 | 136.02 | 112.02 | 94.00 |
| Vernolate | 1929-77-7 | C10H21NOS | 9.30 | 86.06 | 161.09 | 146.10 |
| Propham | 122-42-9 | C10H13NO2 | 9.37 | 137.05 | 179.09 | 120.08 |
| Etridiazole | 2593-15-9 | C5H5N2OSCl3 | 9.40 | 210.95 | 212.95 | 182.92 |
| Pebulate | 1114-71-2 | C10H21NOS | 9.40 | 128.11 | 72.04 | 161.09 |
| cis-1,2,3,6-Tetrahydrophthalimide | 1469-48-3 | C8H9NO2 | 9.57 | 151.06 | 123.07 | 122.06 |
| Chloroneb | 2675-77-6 | C8H8O2Cl2 | 9.77 | 190.97 | 192.96 | 205.99 |
| Tebuthiuron | 34014-18-1 | C9H16N4OS | 9.86 | 156.06 | 89.02 | 171.08 |
| Fenobucarb | 3766-81-2 | C12H17NO2 | 9.93 | 121.06 | 91.05 | 93.07 |
| Pentachlorobenzene | 608-93-5 | C6HCl5 | 9.95 | 247.85 | 251.85 | 249.85 |
| Isoprocarb | 2631-40-5 | C11H15NO2 | 9.98 | 121.06 | 136.09 | 103.05 |
| Molinate | 2212-67-1 | C9H17NOS | 10.01 | 126.09 | 187.10 | 98.10 |
| Heptenophos | 23560-59-0 | C9H12CLO4P | 10.30 | 124.00 | 215.05 | 200.02 |
| Chlorfenprop-methyl | 14437-17-3 | C10H10O2Cl2 | 10.43 | 165.01 | 196.03 | 167.00 |
| Omethoate | 1113-02-6 | C5H12NO4PS | 10.47 | 156.00 | 110.01 | 140.98 |
| Propoxur | 114-26-1 | C11H15NO3 | 10.57 | 110.04 | 82.04 | 152.08 |
| Tecnazene | 117-18-0 | C6HNO2CL4 | 10.59 | 200.88 | 177.91 | 260.87 |
| Propachlor | 1918-16-7 | C11H14NOCl | 10.61 | 120.08 | 176.11 | 169.03 |
| Diphenylamine | 122-39-4 | C12H11N | 10.70 | 169.09 | 167.07 | 168.08 |
| Ethoprophos | 13194-48-4 | C8H19O2PS2 | 10.77 | 157.96 | 199.00 | 200.01 |
| Tributyl phosphate | 126-73-8 | C12H27O4P | 10.78 | 98.98 | 155.05 | 124.10 |
| Cycloate | 1134-23-2 | C11H21NOS | 10.79 | 154.12 | 155.13 | 72.04 |
| 2,3,5,6-Tetrachloroaniline | 3481-20-7 | C6H3Cl4N | 10.80 | 230.90 | 232.90 | 157.96 |
| Atrazine-desethyl | 6190-65-4 | C6H10N5Cl | 11.00 | 172.04 | 145.01 | 187.06 |
| Dicrotophos | 141-66-2 | C8H16NO5P | 11.07 | 127.02 | 193.03 | 111.07 |
| Methabenzthiazuron | 18691-97-9 | C10H11N3OS | 11.07 | 136.02 | 164.04 | 135.01 |
| Trifluralin | 1582-09-8 | C13H16N3O4F3 | 11.08 | 264.02 | 306.07 | 248.03 |
| Bendiocarb | 22781-23-3 | C11H13NO4 | 11.09 | 151.04 | 126.03 | 223.08 |
| Benfluralin | 1861-40-1 | C13H16F3N3O4 | 11.12 | 292.05 | 276.06 | 318.11 |
| Sulfotep | 3689-24-5 | C8H20O5P2S2 | 11.20 | 322.02 | 209.90 | 173.96 |
| Cadusafos | 95465-99-9 | C10H23O2PS2 | 11.25 | 158.97 | 130.94 | 213.02 |
| Tebutam | 35256-85-0 | C15H23NO | 11.27 | 91.05 | 190.12 | 233.18 |
| Promecarb | 2631-37-0 | C12H17NO2 | 11.27 | 135.08 | 107.09 | 150.10 |
| Phorate | 298-02-2 | C7H17O2PS3 | 11.34 | 75.03 | 230.97 | 260.01 |
| α-Hexachlorocyclohexane | 319-84-6 | C6H6Cl6 | 11.95 | 180.94 | 145.97 | 218.91 |
| Atratone | 1610-17-9 | C9H17N5O | 11.61 | 169.10 | 154.07 | 211.14 |
| 3,4,5-Trimethacarb | 2686-99-9 | C11H15NO2 | 11.69 | 121.06 | 91.05 | 136.09 |
| Dicloran | 99-30-9 | C6H4Cl2N2O2 | 11.70 | 175.97 | 159.97 | 207.96 |
| Pentachloroanisole | 1825-21-4 | C7H3Cl5O | 11.72 | 264.84 | 238.84 | 279.86 |
| Ethoxyquin | 91-53-2 | C14H19NO | 11.72 | 202.12 | 174.09 | 203.13 |
| Prometon | 1610-18-0 | C10H19N5O | 11.73 | 168.09 | 210.13 | 225.16 |
| Atrazine | 1912-24-9 | C8H14ClN5 | 11.84 | 200.07 | 202.07 | 173.05 |
| Monolinuron | 1746-81-2 | C9H11ClN2O2 | 11.89 | 126.01 | 152.10 | 214.05 |
| Propazine | 139-40-2 | C9H16N5Cl | 11.92 | 214.08 | 187.06 | 229.11 |
| Clomazone | 81777-89-1 | C12H14ClNO2 | 11.94 | 204.10 | 89.04 | 125.02 |
| Terbumeton | 33693-04-8 | C10H19N5O | 11.95 | 210.13 | 169.10 | 225.16 |
| β-Hexachlorocyclohexane | 319-85-7 | C6H6Cl6 | 11.99 | 180.94 | 145.97 | 218.91 |
| Aminocarb | 2032-59-9 | C11H16N2O2 | 12.04 | 151.10 | 136.08 | 150.09 |
| Isocarbamid | 30979-48-7 | C8H15N3O2 | 12.05 | 142.06 | 130.06 | 113.03 |
| Cyromazine | 66215-27-8 | C6H10N6 | 12.06 | 151.07 | 165.09 | 166.10 |
| γ-Hexachlorocyclohexane | 58-89-9 | C6H6Cl6 | 12.12 | 180.94 | 145.97 | 218.91 |
| Propetamphos | 31218-83-4 | C10H20NO4PS | 12.12 | 138.01 | 193.98 | 222.03 |
| Cycluron | 2163-69-1 | C11H22N2O | 12.13 | 198.17 | 127.09 | 169.13 |
| Terbuthylazine | 5915-41-3 | C9H16N5Cl | 12.14 | 186.05 | 188.05 | 201.08 |
| Terbufos | 13071-79-9 | C9H21O2PS3 | 12.16 | 230.97 | 174.91 | 202.94 |
| Cyanophos | 2636-26-2 | C9H10NO3PS | 12.17 | 243.01 | 124.98 | 109.00 |
| Trietazine | 1912-26-1 | C9H16N5Cl | 12.17 | 200.07 | 214.09 | 229.11 |
| Quintozene | 82-68-8 | C6NO2Cl5 | 12.23 | 213.87 | 248.84 | 294.83 |
| Fonofos | 944-22-9 | C10H15OPS2 | 12.27 | 246.03 | 137.02 | 108.99 |
| Pyroquilon | 57369-32-1 | C11H11NO | 12.28 | 173.08 | 144.08 | 172.08 |
| Dinoterb | 1420-07-1 | C10H12N2O5 | 12.35 | 225.05 | 177.04 | 161.05 |
| Pyrimethanil | 53112-28-0 | C12H13N3 | 12.35 | 198.10 | 199.11 | 183.08 |
| Diazinon | 333-41-5 | C12H21N2O3PS | 12.36 | 179.12 | 199.06 | 304.10 |
| Flufenoxuron | 101463-69-8 | C21H11CLF6N2O3 | 12.46 | 331.00 | 268.04 | 296.03 |
| Disulfoton | 298-04-4 | C8H19O2PS3 | 12.51 | 88.03 | 153.01 | 141.97 |
| Paraoxon-methyl | 950-35-6 | C8H10NO6P | 12.52 | 230.02 | 247.02 | 200.02 |
| Secbumeton | 26259-45-0 | C10H19N5O | 12.52 | 196.12 | 169.10 | 210.13 |
| Aziprotryne | 4658-28-0 | C7H11N7S | 12.53 | 182.05 | 139.01 | 225.08 |
| Dinitramine | 29091-05-2 | C11H13F3N4O4 | 12.53 | 305.09 | 244.06 | 261.06 |
| Fenfuram | 24691-80-3 | C12H11NO2 | 12.57 | 201.08 | 184.05 | 109.03 |
| δ-Hexachlorocyclohexane | 319-86-8 | C6H6Cl6 | 12.61 | 180.94 | 145.97 | 218.91 |
| Mexacarbate | 315-18-4 | C12H18N2O2 | 12.63 | 165.11 | 164.11 | 222.14 |
| Isazofos | 42509-80-8 | C7H13N3O3PSCl | 12.66 | 162.04 | 161.03 | 177.01 |
| Chlorothalonil | 1897-45-6 | C8Cl4N2 | 12.71 | 263.88 | 193.94 | 228.91 |
| Triallate | 2303-17-5 | C10H16CL3NOS | 12.71 | 268.03 | 270.03 | 142.92 |
| Tebupirimfos | 96182-53-5 | C13H23N2O3PS | 12.82 | 234.02 | 261.05 | 276.07 |
| Musk ambrette | 83-66-9 | C12H16N2O5 | 12.83 | 253.08 | 251.10 | 268.10 |
| Oxabetrinil | 74782-23-3 | C12H12N2O3 | 12.85 | 73.03 | 103.04 | 114.03 |
| Iprobenfos | 26087-47-8 | C13H21O3PS | 12.87 | 204.00 | 171.02 | 246.05 |
| Fluroxypyr | 69377-81-7 | C7H5N2O3FCl2 | 12.92 | 180.97 | 208.97 | 195.96 |
| Pirimicarb | 23103-98-2 | C11H18N4O2 | 12.95 | 238.14 | 166.10 | 137.07 |
| Monalide | 7287-36-7 | C13H18NOCl | 12.95 | 197.06 | 127.01 | 239.11 |
| Furmecyclox | 60568-05-0 | C14H21NO3 | 12.98 | 123.04 | 251.15 | 124.05 |
| Benoxacor | 98730-04-2 | C11H11NO2Cl2 | 12.99 | 120.04 | 259.02 | 261.01 |
| Pentachloroaniline | 527-20-8 | C6H2Cl5N | 13.14 | 262.86 | 191.92 | 229.89 |
| Benfuresate | 68505-69-1 | C12H16O4S | 13.17 | 163.08 | 121.06 | 256.08 |
| Dioxacarb | 6988-21-2 | C11H13NO4 | 13.17 | 121.03 | 165.05 | 166.06 |
| Cyprazine | 22936-86-3 | C9H14N5Cl | 13.24 | 212.07 | 170.02 | 226.08 |
| Phosphamidon | 13171-21-6 | C10H19NO5PCl | 13.25 | 138.09 | 193.02 | 264.10 |
| Dichlorprop | 120-36-5 | C9H8O3Cl2 | 13.26 | 161.96 | 132.96 | 188.99 |
| Dichlofenthion | 97-17-6 | C10H13CL2O3PS | 13.26 | 222.94 | 250.97 | 279.00 |
| Fenthion | 55-38-9 | C10H15O3PS2 | 13.26 | 222.94 | 250.97 | 279.00 |
| Propanil | 709-98-8 | C9H9NOCl2 | 13.26 | 160.98 | 162.98 | 219.00 |
| 2,4-DB | 94-82-6 | C10H10O3Cl2 | 13.26 | 161.96 | 125.99 | 97.99 |
| Chlorthiamid | 1918-13-4 | C7H5Cl2NS | 13.29 | 169.98 | 171.98 | 204.95 |
| Dimethachlor | 50563-36-5 | C13H18NO2Cl | 13.29 | 197.06 | 148.08 | 134.10 |
| Metribuzin | 21087-64-9 | C8H14N4OS | 13.31 | 198.07 | 144.05 | 182.04 |
| Dimethenamid | 87674-68-8 | C12H18NO2SCl | 13.32 | 154.07 | 230.04 | 232.04 |
| Bromobutide | 74712-19-9 | C15H22NOBr | 13.35 | 119.09 | 120.08 | 232.17 |
| Terbucarb | 1918-11-2 | C17H27NO2 | 13.44 | 205.16 | 177.13 | 220.18 |
| Malaoxon | 1634-78-2 | C10H19O7PS | 13.46 | 268.02 | 194.99 | 238.98 |
| Vinclozolin | 50471-44-8 | C12H9Cl2NO3 | 13.48 | 178.04 | 212.00 | 285.10 |
| Parathion-methyl | 298-00-0 | C8H10NO5PS | 13.49 | 263.00 | 124.98 | 245.99 |
| Chlorpyrifos-methyl | 5598-13-0 | C7H7Cl3NO3PS | 13.50 | 285.93 | 287.92 | 289.92 |
| Transfluthrin | 118712-89-3 | C15H12O2F4Cl2 | 13.54 | 163.02 | 127.03 | 335.05 |
| Simetryn | 1014-70-6 | C8H15N5S | 13.56 | 213.10 | 155.04 | 170.05 |
| Fuberidazole | 3878-19-1 | C11H8N2O | 13.57 | 184.06 | 156.07 | 183.06 |
| Tolclofos-methyl | 57018-04-9 | C9H11O3PSCL2 | 13.61 | 264.98 | 249.96 | 266.98 |
| Alachlor | 15972-60-8 | C14H20NO2Cl | 13.67 | 188.11 | 202.12 | 160.11 |
| Ametryn | 834-12-8 | C9H17N5S | 13.67 | 227.12 | 170.05 | 185.07 |
| Heptachlor | 76-44-8 | C10H5CL7 | 13.72 | 269.81 | 100.01 | 336.85 |
| Prometryn | 7287-19-6 | C10H19N5S | 13.75 | 241.13 | 184.07 | 199.09 |
| Acetochlor | 34256-82-1 | C14H20NO2Cl | 13.76 | 223.08 | 162.10 | 174.10 |
| Paraoxon-ethyl | 311-45-5 | C10H14NO6P | 13.77 | 275.05 | 247.02 | 139.05 |
| Metalaxyl | 57837-19-1 | C15H21NO4 | 13.78 | 160.11 | 206.12 | 146.10 |
| Tridiphane | 58138-08-2 | C10H7OCl5 | 13.84 | 186.97 | 172.96 | 284.92 |
| Octachlorodipropyl ether | 127-90-2 | C6H6OCl8 | 13.89 | 129.91 | 108.96 | 142.92 |
| Prosulfocarb | 52888-80-9 | C14H21NOS | 13.89 | 128.11 | 86.06 | 251.13 |
| Fenpropidin | 67306-00-7 | C19H31N | 13.97 | 98.10 | 273.24 | 258.22 |
| 1-naphthylacetamide | 86-86-2 | C12H11NO | 14.05 | 141.07 | 142.08 | 185.08 |
| Dithiopyr | 97886-45-8 | C15H16NO2F5S2 | 14.05 | 306.05 | 258.05 | 354.06 |
| Orbencarb | 34622-58-7 | C12H16NOSCl | 14.08 | 222.09 | 125.02 | 100.08 |
| Terbutryn | 886-50-0 | C10H19N5S | 14.08 | 226.11 | 185.07 | 170.05 |
| Spiroxamine | 118134-30-8 | C18H35NO2 | 14.11 | 100.11 | 126.13 | 198.15 |
| Methiocarb | 2032-65-7 | C11H15NO2S | 14.15 | 168.06 | 153.04 | 154.04 |
| Fenitrothion | 122-14-5 | C9H12NO5PS | 14.16 | 260.01 | 124.98 | 277.02 |
| Pirimiphos-methyl | 29232-93-7 | C11H20N3O3PS | 14.19 | 290.07 | 276.06 | 305.10 |
| Methiocarb sulfone | 2179-25-1 | C11H15NO4S | 14.22 | 200.05 | 197.03 | 197.03 |
| Ethofumesate | 26225-79-6 | C13H18O5S | 14.22 | 207.10 | 161.06 | 179.07 |
| Linuron | 330-55-2 | C9H10N2O2Cl2 | 14.27 | 159.97 | 61.05 | 248.01 |
| Probenazole | 27605-76-1 | C10H9NO3S | 14.33 | 130.07 | 103.04 | 158.06 |
| Noruron | 18530-56-8 | C13H22N2O | 14.34 | 153.10 | 193.13 | 207.15 |
| Quinoclamine | 2797-51-5 | C10H6NO2Cl | 14.37 | 172.04 | 144.04 | 207.01 |
| Dipropetryn | 4147-51-7 | C11H21N5S | 14.38 | 255.15 | 222.17 | 184.07 |
| Malathion | 121-75-5 | C10H19O6PS2 | 14.41 | 124.98 | 99.01 | 173.08 |
| Thiobencarb | 28249-77-6 | C12H16ClNOS | 14.44 | 257.06 | 100.08 | 125.02 |
| Diethofencarb | 87130-20-9 | C14H21NO4 | 14.51 | 267.15 | 225.10 | 168.03 |
| Phorate sulfoxide | 2588-03-6 | C7H17O3PS3 | 14.57 | 124.93 | 170.97 | 199.00 |
| Metolachlor | 51218-45-2 | C15H22NO2Cl | 14.61 | 162.13 | 211.08 | 238.10 |
| Fenpropimorph | 67564-91-4 | C20H33NO | 14.67 | 128.11 | 110.10 | 173.13 |
| Cyanazine | 21725-46-2 | C9H13ClN6 | 14.69 | 225.07 | 212.06 | 240.09 |
| Chlorpyrifos | 2921-88-2 | C9H11CL3NO3PS | 14.71 | 196.92 | 257.90 | 313.96 |
| Parathion | 56-38-2 | C10H14NO5PS | 14.73 | 291.03 | 155.00 | 185.99 |
| Flufenacet | 142459-58-3 | C14H13N3O2F4S | 14.79 | 210.98 | 136.06 | 151.08 |
| Rabenzazol | 40341-04-6 | C12H12N4 | 14.79 | 212.11 | 170.07 | 195.08 |
| 4,4′-Dichlorobenzophenone | 90-98-2 | C13H8Cl2O | 14.80 | 138.99 | 110.99 | 249.99 |
| Triadimefon | 43121-43-3 | C14H16ClN3O2 | 14.80 | 208.03 | 210.02 | 181.02 |
| Chlorthal-dimethyl | 1861-32-1 | C10H6CL4O4 | 14.86 | 300.88 | 298.88 | 331.90 |
| Dicapthon | 2463-84-5 | C8H9NO5PSCl | 14.86 | 261.99 | 124.98 | 216.00 |
| Isofenphos-oxon | 31120-85-1 | C15H24NO5P | 14.87 | 200.99 | 229.03 | 272.07 |
| Isocarbophos | 24353-61-5 | C11H16NO4PS | 14.90 | 135.99 | 230.00 | 121.03 |
| Tetraconazole | 112281-77-3 | C13H11Cl2F4N3O | 14.92 | 336.05 | 136.01 | 170.98 |
| Isobenzan | 297-78-9 | C9H4CL8O | 15.00 | 407.78 | 274.86 | 310.83 |
| Flurochloridone | 61213-25-0 | C12H10Cl2F3NO | 15.01 | 174.05 | 311.01 | 313.01 |
| Fenson | 80-38-6 | C12H9O3SCl | 15.03 | 267.99 | 141.00 | 269.99 |
| Pyracarbolid | 24691-76-7 | C13H15NO2 | 15.13 | 125.06 | 217.11 | 97.03 |
| Dodemorph | 1593-77-7 | C18H35NO | 15.13 | 154.12 | 238.22 | 281.27 |
| Mgk 264 | 113-48-4 | C17H25NO2 | 15.14, 15.45 | 164.07 | 209.14 | 210.15 |
| Butralin | 33629-47-9 | C14H21N3O4 | 15.16 | 266.11 | 236.10 | 220.11 |
| Carbaryl | 63-25-2 | C12H11NO2 | 15.16 | 144.06 | 115.05 | 116.06 |
| Diphenamid | 957-51-7 | C16H17NO | 15.21 | 167.09 | 165.07 | 152.06 |
| Pirimiphos-ethyl | 23505-41-1 | C13H24N3O3PS | 15.29 | 168.06 | 318.10 | 333.13 |
| Isodrin | 465-73-6 | C12H8Cl6 | 15.36 | 192.94 | 361.88 | 194.93 |
| Aldrin | 309-00-2 | C12H8CL6 | 15.36 | 260.86 | 290.93 | 326.91 |
| Isopropalin | 33820-53-0 | C15H23N3O4 | 15.36 | 280.13 | 238.08 | 264.13 |
| Cyprodinil | 121552-61-2 | C14H15N3 | 15.41 | 224.12 | 225.13 | 208.09 |
| Isofenphos-methyl | 99675-03-3 | C14H22NO4PS | 15.42 | 199.02 | 230.99 | 241.06 |
| Octachlorostyrene | 29082-74-4 | C8Cl8 | 15.54 | 305.81 | 270.84 | 379.74 |
| Metazachlor | 67129-08-2 | C14H16ClN3O | 15.56 | 209.06 | 133.09 | 211.06 |
| Dimethametryn | 22936-75-0 | C11H21N5S | 15.58 | 212.10 | 185.07 | 240.13 |
| Pendimethalin | 40487-42-1 | C13H19N3O4 | 15.60 | 252.10 | 191.07 | 162.08 |
| Disulfoton-sulfone | 2497-6-5 | C8H19O4PS3 | 15.62 | 153.01 | 124.98 | 213.02 |
| Phorate sulfone | 2588-04-7 | C7H17O4PS3 | 15.62 | 199.00 | 124.98 | 170.97 |
| Terbufos sulfone | 56070-16-7 | C9H21O4PS3 | 15.62 | 153.01 | 199.00 | 263.97 |
| Paclobutrazol | 76738-62-0 | C15H20ClN3O | 15.64 | 236.06 | 138.02 | 167.03 |
| Penconazole | 66246-88-6 | C13H15N3Cl2 | 15.64 | 248.09 | 160.97 | 158.98 |
| Chlozolinate | 84332-86-5 | C13H11NO5Cl2 | 15.72 | 186.96 | 260.98 | 188.96 |
| Pyrifenox | 88283-41-4 | C14H12N2OCl2 | 15.72 | 262.01 | 186.96 | 227.04 |
| Tolylfluanid | 731-27-1 | C10H13N2O2FS2Cl2 | 15.75 | 237.97 | 181.08 | 239.96 |
| Fosthiazate | 98886-44-3 | C9H18NO3PS2 | 15.80 | 195.01 | 166.02 | 226.98 |
| Phosfolan | 947-02-4 | C7H14NO3PS2 | 15.80 | 139.96 | 167.99 | 266.98 |
| Allethrin | 584-79-2 | C19H26O3 | 15.84 | 123.12 | 91.05 | 136.09 |
| Isofenphos | 25311-71-1 | C15H24NO4PS | 15.84 | 213.03 | 184.99 | 216.97 |
| Captan | 133-06-2 | C9H8NO2SCl3 | 15.85 | 149.05 | 105.03 | 116.91 |
| Fipronil | 120068-37-3 | C12H4Cl2F6N4OS | 15.88 | 366.94 | 368.94 | 212.95 |
| Diclocymet | 139920-32-4 | C15H18N2OCl2 | 15.90, 16.38 | 221.05 | 172.99 | 277.11 |
| Quinalphos | 13593-03-8 | C12H15N2O3PS | 15.92 | 146.05 | 157.08 | 173.07 |
| Phenthoate | 2597-03-7 | C12H17O4PS2 | 15.93 | 273.99 | 121.01 | 245.99 |
| Triadimenol | 55219-65-3 | C14H18N3O2Cl | 15.94 | 168.11 | 112.05 | 169.12 |
| Dinobuton | 973-21-7 | C14H18N2O7 | 16.00 | 211.03 | 163.03 | 205.06 |
| Furalaxyl | 57646-30-7 | C17H19NO4 | 16.03 | 242.12 | 152.07 | 146.10 |
| Crotoxyphos | 7700-17-6 | C14H19O6P | 16.06 | 193.03 | 127.02 | 105.07 |
| Procymidone | 32809-16-8 | C13H11NO2Cl2 | 16.11 | 283.02 | 96.06 | 255.02 |
| Chlorbenside | 103-17-3 | C13H10SCl2 | 16.15 | 125.02 | 127.01 | 267.99 |
| Chlorflurenol-methyl | 2536-31-4 | C15H11O3Cl | 16.22 | 215.03 | 152.06 | 274.04 |
| Chlordane | 5103-71-9 | C10H6Cl8 | 16.32, 16.58 | 372.83 | 376.82 | 374.82 |
| Methidathion | 950-37-8 | C6H11N2O4PS3 | 16.33 | 145.01 | 85.04 | 147.00 |
| Haloxyfop-methyl | 69806-40-2 | C16H13ClF3NO4 | 16.39 | 375.05 | 288.00 | 179.98 |
| Bromophos-ethyl | 4824-78-6 | C10H12O3PSCl2Br | 16.41 | 300.85 | 241.87 | 358.91 |
| Procyazine | 32889-48-8 | C10H13N6Cl | 16.43 | 210.05 | 212.05 | 252.09 |
| Disulfoton-sulfoxide | 2497-07-6 | C8H19O3PS3 | 16.61 | 183.98 | 124.98 | 167.98 |
| Tetrachlorvinphos | 22248-79-9 | C10H9O4PCl4 | 16.63 | 328.93 | 203.93 | 239.89 |
| Endosulfan | 959-98-8 | C9H6O3SCl6 | 16.67, 18.37 | 236.84 | 169.97 | 159.98 |
| Mepanipyrim | 110235-47-7 | C14H13N3 | 16.69 | 222.10 | 221.09 | 223.11 |
| Butachlor | 23184-66-9 | C17H26NO2Cl | 16.74 | 176.11 | 188.11 | 160.11 |
| Ditalimfos | 5131-24-8 | C12H14NO4PS | 16.81 | 242.98 | 208.97 | 271.00 |
| TCMTB | 21564-17-0 | C9H6N2S3 | 16.87 | 179.99 | 166.99 | 237.97 |
| Trans-nonachlor | 39765-80-5 | C10H5Cl9 | 16.90 | 408.78 | 404.79 | 271.81 |
| Chlorfenson | 80-33-1 | C12H8CL2O3S | 16.94 | 174.96 | 176.96 | 301.96 |
| Fenamiphos | 22224-92-6 | C13H22NO3PS | 16.95 | 303.11 | 260.05 | 217.01 |
| Picoxystrobin | 117428-22-5 | C18H16NO4F3 | 16.96 | 303.05 | 173.06 | 335.08 |
| Napropamide | 15299-99-7 | C17H21NO2 | 17.00 | 271.16 | 72.08 | 115.05 |
| Hexaconazole | 79983-71-4 | C14H17Cl2N3O | 17.06 | 213.99 | 231.03 | 174.97 |
| Flutolanil | 66332-96-5 | C17H16NO2F3 | 17.07 | 173.02 | 281.07 | 323.11 |
| Prothiophos | 34643-46-4 | C11H15O2PS2Cl2 | 17.18 | 308.99 | 238.92 | 266.95 |
| Isoprothiolane | 50512-35-1 | C12H18O4S2 | 17.19 | 117.99 | 161.98 | 290.06 |
| Profenofos | 41198-08-7 | C11H15BrClO3PS | 17.26 | 338.96 | 205.91 | 207.91 |
| Tricyclazole | 41814-78-2 | C9H7N3S | 17.35 | 189.03 | 135.01 | 161.02 |
| Pretilachlor | 51218-49-6 | C17H26NO2Cl | 17.36 | 162.13 | 202.12 | 238.10 |
| Dieldrin | 60-57-1 | C12H8CL6O | 17.44 | 262.86 | 81.03 | 260.86 |
| Oxadiazon | 19666-30-9 | C15H18N2O3Cl2 | 17.51 | 174.96 | 302.02 | 344.07 |
| Iprovalicarb | 140923-17-7 | C18H28N2O3 | 17.52, 17.82 | 134.10 | 116.07 | 158.12 |
| Carboxin | 5234-68-4 | C12H13NO2S | 17.60 | 235.07 | 218.04 | 143.02 |
| Myclobutanil | 88671-89-0 | C15H17ClN4 | 17.60 | 179.02 | 150.01 | 245.06 |
| p,p'-Dichlorodiphenyldichloroethylene | 72-55-9 | C14H8Cl4 | 17.64 | 315.94 | 247.99 | 245.99 |
| Buprofezin | 69327-76-0 | C16H23N3OS | 17.68 | 175.09 | 171.10 | 249.11 |
| Imazalil | 35554-44-0 | C14H14Cl2N2O | 17.70 | 174.95 | 172.96 | 158.98 |
| Flusilazole | 85509-19-9 | C16H15N3F2Si | 17.70 | 233.06 | 206.05 | 314.10 |
| Methoprotryne | 841-06-5 | C11H21N5OS | 17.72 | 256.12 | 184.07 | 212.10 |
| Azaconazole | 60207-31-0 | C12H11N3O2Cl2 | 17.75 | 216.98 | 144.96 | 174.95 |
| Bupirimate | 41483-43-6 | C13H24N4O3S | 17.79 | 208.14 | 193.14 | 273.10 |
| Imazamethabenz-methyl | 81405-85-8 | C16H20N2O3 | 17.82 | 144.04 | 176.07 | 245.09 |
| Kresoxim-methyl | 143390-89-0 | C18H19NO4 | 17.83 | 116.05 | 131.07 | 206.08 |
| Metamitron | 41394-05-2 | C10H10N4O | 17.85 | 174.09 | 173.08 | 202.08 |
| Isoxathion | 18854-01-8 | C13H16NO4PS | 17.97 | 177.02 | 159.01 | 313.05 |
| Aramite | 140-57-8 | C15H23O4SCl | 17.98 | 185.00 | 175.11 | 319.08 |
| Nitrofen | 1836-75-5 | C12H7Cl2NO3 | 18.02 | 282.98 | 284.98 | 202.02 |
| Endrin | 72-20-8 | C12H8CL6O | 18.09 | 242.95 | 280.93 | 316.90 |
| Endrin aldehyde | 7421-93-4 | C12H8OCl6 | 18.09 | 242.95 | 280.93 | 344.90 |
| Ancymidol | 12771-68-5 | C15H16N2O2 | 18.12 | 228.90 | 107.02 | 215.08 |
| Perthan | 72-56-0 | C18H20Cl2 | 18.15 | 223.15 | 178.08 | 167.09 |
| Chlorfenapyr | 122453-73-0 | C15H11BRCLF3N2O | 18.19 | 247.05 | 363.94 | 361.94 |
| Chloropropylate | 5836-10-2 | C17H16O3Cl2 | 18.38 | 138.99 | 110.99 | 251.00 |
| Chlorobenzilate | 510-15-6 | C16H14O3Cl2 | 18.38 | 138.99 | 251.00 | 252.99 |
| Fenthion sulfoxide | 3761-41-9 | C10H15O4PS2 | 18.51 | 294.01 | 278.99 | 152.98 |
| Diniconazole | 83657-24-3 | C15H17N3OCl2 | 18.55 | 268.00 | 234.04 | 165.01 |
| Flamprop-isopropyl | 52756-22-6 | C19H19NO3FCl | 18.63 | 276.06 | 105.03 | 156.00 |
| p,p'-Dichlorodiphenyldichloroethane | 72-54-8 | C14H10Cl4 | 18.66 | 235.01 | 199.03 | 165.07 |
| Aclonifen | 74070-46-5 | C12H9CLN2O3 | 18.68 | 264.03 | 182.06 | 212.06 |
| o,p'-Dichlorodiphenyltrichloroethane | 789-02-6 | C14H9Cl5 | 18.76 | 235.00 | 165.07 | 237.00 |
| Oxadixyl | 77732-09-3 | C14H18N2O4 | 18.78 | 233.09 | 163.10 | 132.08 |
| Ethion | 563-12-2 | C9H22O4P2S4 | 18.82 | 230.97 | 202.94 | 153.01 |
| Mepronil | 55814-41-0 | C17H19NO2 | 19.07 | 119.05 | 210.07 | 269.14 |
| Triazophos | 24017-47-8 | C12H16N3O3PS | 19.22 | 162.07 | 257.00 | 172.09 |
| Azamethiphos | 35575-96-3 | C9H10ClN2O5PS | 19.34 | 182.99 | 214.97 | 323.97 |
| Ofurace | 58810-48-3 | C14H16NO3Cl | 19.39 | 232.10 | 186.09 | 281.08 |
| Carbophenothion | 786-19-6 | C11H16O2PS3Cl | 19.47 | 341.97 | 170.97 | 199.00 |
| Benalaxyl | 71626-11-4 | C20H23NO3 | 19.55 | 148.11 | 176.11 | 206.12 |
| Tepraloxydim | 149979-41-9 | C17H24NO4Cl | 19.55 | 164.07 | 136.04 | 108.04 |
| Diofenolan | 63837-33-2 | C18H20O4 | 19.56, 19.77 | 186.07 | 131.05 | 225.09 |
| Cyanofenphos | 13067-93-1 | C15H14NO2PS | 19.60 | 141.01 | 169.04 | 185.02 |
| Edifenphos | 17109-49-8 | C14H15O2PS2 | 19.60 | 172.98 | 186.05 | 310.02 |
| Quinoxyfen | 124495-18-7 | C15H8NOFCl2 | 19.63 | 306.99 | 237.06 | 161.00 |
| Endosulfan sulfate | 1031-07-8 | C9H6CL6O4S | 19.69 | 271.81 | 236.84 | 269.81 |
| Propiconazol | 60207-90-1 | C15H17Cl2N3O2 | 19.70, 19.91 | 172.95 | 259.03 | 261.03 |
| Norflurazon | 27314-13-2 | C12H9N3OF3Cl | 19.74 | 303.04 | 173.03 | 302.03 |
| Fenhexamid | 126833-17-8 | C14H17Cl2NO2 | 19.79 | 176.97 | 178.97 | 301.06 |
| p,p'-Dichlorodiphenyltrichloroethane | 50-29-3 | C14H9Cl5 | 19.84 | 235.00 | 199.03 | 165.07 |
| Trifloxystrobin | 141517-21-7 | C20H19F3N2O4 | 19.92 | 116.05 | 190.05 | 186.05 |
| Hexazinone | 51235-04-2 | C12H20N4O2 | 20.17 | 171.09 | 71.06 | 128.08 |
| Tebuconazol | 107534-96-3 | C16H22ClN3O | 20.26 | 250.07 | 125.02 | 163.03 |
| Chloridazon | 1698-60-8 | C10H8ClN3O | 20.26 | 220.03 | 221.04 | 222.02 |
| Nuarimol | 63284-71-9 | C17H12N2OFCl | 20.28 | 235.03 | 203.06 | 314.06 |
| Diclofop-methyl | 51338-27-3 | C16H14Cl2O4 | 20.39 | 340.03 | 254.98 | 252.98 |
| Triphenyl phosphate | 115-86-6 | C18H15O4P | 20.49 | 325.06 | 169.06 | 233.04 |
| Piperonyl butoxide | 51-03-6 | C19H30O5 | 20.62 | 176.08 | 161.06 | 177.09 |
| Oxycarboxin | 5259-88-1 | C12H13NO4S | 20.68 | 175.01 | 250.03 | 267.06 |
| Resmethrin | 10453-86-8 | C22H26O3 | 20.70 | 143.09 | 128.06 | 171.08 |
| Zoxamide | 156052-68-5 | C14H16NO2Cl3 | 20.83 | 186.97 | 258.04 | 242.01 |
| Mefenpyr-diethyl | 135590-91-9 | C16H18Cl2N2O4 | 21.02 | 271.00 | 227.01 | 299.03 |
| Benzoylprop-ethyl | 22212-55-1 | C18H17NO3Cl2 | 21.12 | 105.03 | 292.03 | 260.02 |
| Spiromesifen | 283594-90-1 | C23H30O4 | 21.14 | 254.13 | 231.10 | 226.13 |
| Endrin ketone | 53494-70-5 | C12H8OCl6 | 21.16 | 314.91 | 281.93 | 242.95 |
| Fenamiphos sulfone | 31972-44-8 | C13H22NO5PS | 21.27 | 292.04 | 320.07 | 214.06 |
| Bromuconazole | 116255-48-2 | C13H12BrCl2N3O | 21.31, 22.12 | 172.95 | 294.91 | 174.95 |
| Fenpiclonil | 74738-17-3 | C11H6N2Cl2 | 21.32 | 235.99 | 201.02 | 237.99 |
| Phosmet | 732-11-6 | C11H12NO4PS2 | 21.37 | 160.04 | 104.03 | 133.03 |
| Bromopropylate | 18181-80-1 | C17H16O3Br2 | 21.48 | 184.94 | 182.94 | 338.90 |
| Tetramethrin | 7696-12-0 | C19H25NO4 | 21.61 | 164.07 | 107.05 | 123.12 |
| Picolinafen | 137641-05-5 | C19H12N2O2F4 | 21.61 | 238.05 | 145.03 | 376.08 |
| Bifenthrin | 82657-04-3 | C23H22ClF3O2 | 21.64 | 181.10 | 165.07 | 182.10 |
| Piperophos | 24151-93-7 | C14H28NO3PS2 | 21.68 | 122.10 | 140.11 | 320.14 |
| 4,4′-Methoxychlor | 72-43-5 | C16H15O2CL3 | 21.73 | 227.11 | 212.08 | 228.11 |
| Bifenazate | 149877-41-8 | C17H20N2O3 | 21.73 | 300.15 | 258.10 | 196.08 |
| Fenpropathrin | 39515-41-8 | C22H23NO3 | 21.83 | 181.06 | 209.08 | 265.07 |
| Etoxazole | 153233-91-1 | C21H23F2NO2 | 21.91 | 300.12 | 187.11 | 330.13 |
| Tebufenpyrad | 119168-77-3 | C18H24N3OCl | 21.94 | 333.16 | 171.03 | 276.09 |
| Fenamidone | 161326-34-7 | C17H17N3OS | 21.95 | 268.09 | 206.07 | 238.11 |
| Dicofol | 115-32-2 | C14H9CL5O | 21.98 | 138.99 | 199.03 | 140.99 |
| Metconazole | 125116-23-6 | C17H22N3OCl | 21.99 | 125.02 | 145.06 | 250.11 |
| Fenazaquin | 120928-09-8 | C20H22N2O | 22.00 | 145.10 | 117.07 | 160.12 |
| Tetradifon | 116-29-0 | C12H6O2SCl4 | 22.36 | 226.89 | 228.89 | 158.97 |
| Furathiocarb | 65907-30-4 | C18H26N2O5S | 22.54 | 163.08 | 194.04 | 325.13 |
| Phosalone | 2310-17-0 | C12H15NO4PS2Cl | 22.68 | 182.00 | 121.04 | 366.99 |
| Pyriproxyfen | 95737-68-1 | C20H19NO3 | 22.88 | 136.08 | 226.10 | 137.08 |
| Mirex | 2385-85-5 | C10Cl12 | 22.96 | 271.81 | 269.81 | 331.81 |
| Mefenacet | 73250-68-7 | C16H14N2O2S | 23.04 | 192.01 | 136.02 | 120.08 |
| Cyhalothrin | 68085-85-8 | C23H19ClF3NO3 | 23.13, 23.49 | 141.05 | 197.03 | 161.06 |
| Tralkoxydim | 87820-88-0 | C20H27NO3 | 23.17 | 137.04 | 227.13 | 283.16 |
| Fenarimol | 60168-88-9 | C17H12N2OCl2 | 23.58 | 251.00 | 219.03 | 252.99 |
| Trifenmorph | 1420-06-0 | C23H23NO | 23.65 | 243.12 | 228.09 | 239.09 |
| Azinphos-ethyl | 2642-71-9 | C12H16N3O3PS2 | 23.85 | 132.04 | 104.05 | 160.05 |
| Pyrazophos | 13457-18-6 | C14H20N3O5PS | 23.88 | 221.08 | 265.09 | 193.05 |
| Acrinathrin | 101007-06-1 | C26H21F6NO5 | 23.90 | 181.06 | 208.08 | 289.07 |
| Fluoroglycofen-ethyl | 77501-90-7 | C18H13NO7F3Cl | 23.96 | 343.99 | 223.04 | 447.03 |
| Fenoxaprop-ethyl | 66441-23-4 | C18H16NO5Cl | 24.25 | 288.04 | 182.06 | 361.07 |
| Bitertanol | 55179-31-2 | C20H23N3O2 | 24.59 | 170.07 | 168.11 | 171.08 |
| Spirodiclofen | 148477-71-8 | C21H24Cl2O4 | 24.74 | 259.05 | 312.03 | 156.96 |
| Permethrin | 61949-76-6 | C21H20CL2O3 | 24.78, 25.03 | 183.08 | 163.01 | 127.03 |
| Pyridaben | 96489-71-3 | C19H25ClN2OS | 24.96 | 147.12 | 117.07 | 309.08 |
| Fluquinconazole | 136426-54-5 | C16H8N5OFCl2 | 25.13 | 340.04 | 298.02 | 286.02 |
| Coumaphos | 56-72-4 | C14H16CLO5PS | 25.16 | 362.01 | 210.01 | 225.98 |
| Prochloraz | 67747-09-5 | C15H16N3O2Cl3 | 25.28 | 180.11 | 265.95 | 308.00 |
| Butafenacil | 134605-64-4 | C20H18N2O6F3Cl | 25.63 | 331.01 | 123.99 | 179.98 |
| Prallethrin | 23031-36-9 | C19H24O3 | 25.83 | 123.12 | 81.07 | 105.07 |
| Cyfluthrin | 68359-37-5 | C22H18NO3FCl2 | 25.94, 26.13, 26.26, 26.35 | 206.06 | 199.06 | 163.01 |
| Cypermethrin | 52315-07-8 | C22H19Cl2NO3 | 26.51, 26.71, 26.83, 26.93 | 181.06 | 163.01 | 127.03 |
| Boscalid | 188425-85-6 | C18H12Cl2N2O | 26.53 | 342.03 | 111.99 | 139.99 |
| Quizalofop-ethyl | 76578-14-8 | C19H17CLN2O4 | 26.75 | 372.09 | 243.03 | 163.01 |
| Flucythrinate | 70124-77-5 | C26H23F2NO4 | 26.93, 27.30 | 157.05 | 199.09 | 225.08 |
| Etofenprox | 80844-07-1 | C25H28O3 | 27.03 | 163.11 | 135.08 | 164.12 |
| Pyridalyl | 179101-81-6 | C18H14NO3F3Cl4 | 27.18 | 204.06 | 148.04 | 176.03 |
| Fenvalerate | 51630-58-1 | C25H22NO3Cl | 28.21, 28.61 | 419.13 | 125.02 | 167.06 |
| Flumioxazin | 103361-09-7 | C19H15FN2O4 | 28.25 | 354.10 | 259.05 | 326.11 |
| Pyraclostrobin | 175013-18-0 | C19H18N3O4Cl | 28.34 | 132.04 | 104.05 | 164.07 |
| Tau-fluvalinate | 102851-06-9 | C26H22ClF3N2O3 | 28.62, 28.75 | 250.06 | 252.06 | 205.99 |
| Difenoconazole | 119446-68-3 | C19H17N3O3Cl2 | 28.95, 29.07 | 323.02 | 266.98 | 264.98 |
| Deltamethrin | 52918-63-5 | C22H19Br2NO3 | 29.21, 29.56 | 171.99 | 173.99 | 252.90 |
| Azoxystrobin | 131860-33-8 | C22H17N3O5 | 30.02 | 344.10 | 372.10 | 388.09 |
| Dimethomorph | 110488-70-5 | C21H22ClNO4 | 30.06 | 301.06 | 303.06 | 387.12 |