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. Author manuscript; available in PMC: 2022 Jun 22.
Published in final edited form as: Chem Rev. 2021 Apr 12;121(8):4309–4372. doi: 10.1021/acs.chemrev.0c01088

Figure 13. Design principle for strong hydrogels – synchronize stiffening and fracture of multiple polymer chains:

Figure 13.

a. definition and measurement of the tensile strength. A and a are the cross-section areas of the sample in the undeformed and deformed states, and F is applied tensile force. b. the simultaneous stiffening and fracture of substantial polymer chains give a high tensile strength759. Ff is the tensile force at the failure of the sample. c. the nominal tensile strength sc increases with the decrease of the defect size D up to a critical value Dc, below which the tensile strength is defect-insensitive760,761.