TABLE 3.
Quantum yields of the cyano fragment [Pt(CN)4]2− derived from [Pt(CN)4(X)(Y)] under light irradiation at various wavelength [adapted from Vogler et al. (1978a)].
[Pt(CN)4(N3)(Cl)] | [Pt(CN)4(N3)(Br)] | [Pt(CN)4(Cl)2] | [Pt(CN)4(Br)2] | |||
---|---|---|---|---|---|---|
Solvent | Ethanol | Water | Ethanol | Water | Ethanol | Ethanol |
Irradiation wavelength | 300 nm | 300 nm | 300 nm | 300 nm | 254 nm | 254 nm |
Quantum yield | 0.35 ± 0.02 | 0.22 ± 0.02 | 42 ± 0.02 | 0.26 ± 0.02 | 34 ± 0.02 | 25 ± 0.03 |