geoaccumulation
index (Igeo)21−23
|
Igeo = Log2(Ci/(1.5 × Bi)) |
Ci is the measured value of heavy metal
(i) in the sediments, Bi is the geochemical background value of the heavy metal (i) in sedimentary rocks, Bi is
using the background value of soil inorganic elements in Guangdong
Province during “The 7th Five-Year Plan” (Co = 7.0 mg/kg,
V = 65.3 mg/kg, Cu = 17 mg/kg, Pb = 36 mg/kg, Ni = 14.4 mg/kg, As
= 8.9 mg/kg, Cd = 0.056 mg/kg, and Hg = 0.078 mg/kg),24 and the 1.5 is the coefficient to decrease the effects
of variations in the background values; Igeo can be divided into seven grades: |
Igeo ≤ 0 |
0 < Igeo ≤ 1 |
1 < Igeo ≤ 2 |
2 < Igeo ≤ 3 |
3 < Igeo ≤ 4 |
Igeo > 4 |
Igeo > 5 |
unpolluted |
unpolluted to moderately
polluted |
moderately
polluted |
moderately
to heavily polluted |
heavily polluted |
heavily to extremely polluted |
extremely polluted |
contamination
factor (CF)23,25,26
|
CF = Ci/Cn
|
Ci is the heavy metal
(i) content measured in sediments, and Cn is the reference
value of heavy metal (i) in the study using the background
value of soil inorganic elements in Guangdong Province during “The
7th Five-Year Plan”; CF values can be divided into four groups: |
CF < 1 |
1 ≤ CF < 3 |
3 ≤ CF < 6 |
CF ≥ 6 |
low
contamination |
moderate contamination |
considerable contamination |
very
high contamination |
potential ecological
risk index (RI)25,26
|
|
Eri is the potential ecological
risk coefficient of single heavy metal (i), pointing
to the ecological risk level of a single pollutant, and Tr is the response factor of the heavy metal
toxicity coefficient in the order Co = Cu = Pb = Ni = 5, V = 2, Cu
= 5, Pb = 5, Ni = 5, As = 10, Cd = 30, and Hg = 40. The degree of
ecological risk can be classified into the following levels: |
Eri < 40 |
40 ≤ Eri < 80 |
80 ≤ Eri < 160 |
160 ≤ Eri < 320 |
Eri ≥ 320 |
low risk |
moderate risk |
strong risk |
very strong risk |
extreme risk |
RI < 150 |
150 ≤ RI <300 |
300 ≤ RI < 600 |
RI ≥ 600 |
|
low risk |
moderate risk |
strong risk |
very strong risk |
|