Table 3. Photophysical Properties of Compound 4c.
entry | solvent | absorptiona λmax,abs (nm) | emissiona λmax,emi (nm) | molar extinction coefficient × 104 (ε) π–π* | Stoke’s shift Δν̅ (cm–1)b | quantum yield (Φf)c |
---|---|---|---|---|---|---|
1 | CH3CN | 228, 263 | 414 | 5.00985 | 19 705 | 0.3681 |
2 | MeOH | 230, 264 | 436 | 5.12955 | 20 542 | 0.3195 |
3 | THF | 247, 317 | 409 | 1.67091 | 16 035 | 0.1063 |
4 | dioxane | 271, 317 | 408 | 0.97554 | 12 390 | 0.2146 |
5 | toluene | 287, 319 | 407 | 0.56647 | 10 273 | 0.2270 |
Recorded at 298 K.
Stoke’s shift = λmax,abs – λmax,emi [cm –1].
Determined with anthracene as a standard Φf = 0.27 at an excitation wavelength of 246 nm.