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. 2022 Jun 9;7(24):20605–20618. doi: 10.1021/acsomega.2c00674

Table 4. Photophysical Properties of Compound 4k.

entry solvent absorptionaλmax,abs (nm) emissionaλmax,emi (nm) molar extinction coefficient × 104 (ε) π–π* Stoke’s shift Δν̅ (cm–1)b quantum yield (Φf)c
1 CH3CN 231 418 7.6462 19 366 0.1522
2 MeOH 233 463 10.3089 21 320 0.1580
3 THF 249, 357 408 3.41119 15 650 0.2754
4 dioxane 272, 356 407 1.54363 12 194 0.7916
5 toluene 288, 353 408 1.12686 10 212 0.8019
a

Recorded at 298 K.

b

Stoke’s shift = λmax,abs – λmax,emi [cm–1].

c

Determined with anthracene as a standard Φf = 0.27 at an excitation wavelength of 246 nm.