Table 4. Photophysical Properties of Compound 4k.
entry | solvent | absorptionaλmax,abs (nm) | emissionaλmax,emi (nm) | molar extinction coefficient × 104 (ε) π–π* | Stoke’s shift Δν̅ (cm–1)b | quantum yield (Φf)c |
---|---|---|---|---|---|---|
1 | CH3CN | 231 | 418 | 7.6462 | 19 366 | 0.1522 |
2 | MeOH | 233 | 463 | 10.3089 | 21 320 | 0.1580 |
3 | THF | 249, 357 | 408 | 3.41119 | 15 650 | 0.2754 |
4 | dioxane | 272, 356 | 407 | 1.54363 | 12 194 | 0.7916 |
5 | toluene | 288, 353 | 408 | 1.12686 | 10 212 | 0.8019 |
Recorded at 298 K.
Stoke’s shift = λmax,abs – λmax,emi [cm–1].
Determined with anthracene as a standard Φf = 0.27 at an excitation wavelength of 246 nm.