Table 1.
Spectroscopic a and electrochemical b data for phenothiazine-based chemosensors 6–8.
λmax (nm) |
E°Ox1 (V) |
E°Ox2 c (V) |
E°Red (V) |
E°Ox1ONSET (V) |
E°RedONSET (V) |
Egelec (eV) |
|
---|---|---|---|---|---|---|---|
6 | 410 | 0.90 | 1.51 | −1.01 | 0.76 | −0.94 | 1.70 |
7 | 514 | 0.85 | 1.51 | −0.57 | 0.74 | −0.47 | 1.21 |
8 | 531 | 0.84 | 1.50 | −0.39 | 0.71 | −0.27 | 0.98 |
a 1.41 × 10−5 mol L−1 in CH3CN. b 10−3 M in nBu4NPF6 (0.1 M) in CH3CN, scan rate 100 mV s−1, E° versus Ag/AgCl (0.1 M). c shoulder at 1.42 V.