Table 1.

¹H and ¹³C NMR spectral data ¹ of the new compounds 5–8.

C/H	5		6		7		8
1	35.6 t	1.22 m 1.34 m	35.6 t	0.94 m 1.34 m	33.5 t	1.10 m 1.35 m	34.9 t	1.22 m 1.40 m
2	33.8 t	1.57 m 1.76 m	33.8 t	1.20 m 1.73 m	28.2 t	1.99 m 2.05 m	33.8 t	1.54 m 1.76 m
3	77.6 s		76.6 s		77.0 s (78.7) *		77.3 s
4	41.8 s		41.8 s		42.0 s		42.6 s
5	51.3 d	1.38 m	51.7 d	1.40 m	53.5 d (54.5) *	1.08 m	54.6 d	1.08 m
6	21.3 t	1.41 m 1.50 m	19.9 t	1.41 m 1.47 m	20.00 t	1.27 m 1.40 m	20.3 t	1.45 m 1.50 m
7	31.6 t	1.30 m 1.32 m	31.6 t	1.29 m 1.37 m	33.3 t	0.83 m 0.90 m	31.6 t	1.20 m 1.42 m
8	37.9 s		37.8 s		37.6 s		38.1 s
9	47.6 d	1.76 m	47.7 d	1.73 m	46.8 d	1.60 m	47.7 d	1.70 m
10	37.9 s		37.9 s		37.7 s		38.3 s
11	24.1 t	1.92 m 1.93 m	24.4 t	1.89 m 1.91 m	23.8 t	1.80 m 1.96 m	24.5 t	1.91 m 1.95 m
12	123.5 d	5.28 t (3.15)	123.7 d	5.26 t (3.3)	122.4 d	5.39 t (3.2)	123.6 d	5.27 t (3.1)
13	145.1 s		145.2 s		144.9 s		145.2 s
14	40.5 s		40.8 s		37.8 s		40.6 s
15	28.8 t	1.10 m 1.81 m	28.8 t	1.10 m 1.78 m	31.01 t	1.24 m 1.70 m	29.0 t	1.08 m 1.82 m
16	24.4 t	1.61 m 2.03 m	24.5 t	1.59 m 2.02 m	26.1 t	0.99 m 1.00 m	24.1 t	1.64 m 2.04 m
17	43.0 s		43.0 s		42.2 s		42.9 s
18	42.7 d	2.88 dd (13.9, 4.4)	42.7 d	2.86 dd (14.0, 4.5)	39.8 d	3.20 dd (13.6, 4.5)	42.8 d	2.87 dd (13.7, 4.7)
19	47.2 t	1.14 m 1.70 m	47.3 t	1.12 m 1.67 m	46.7 t	1.21 m 1.69 m	47.3 t	1.16 m 1.71 m
20	29.5 s		29.9 s		28.7 s		30.8 s
21	34.9 t	1.22 m 1.34 m	34.9 t	0.95 m 1.33 m	34.9 t	1.08 m 1.33 m	34.7 t	1.22 m 1.35 m
22	34.1 t	1.56 m 1.77 m	34.1 t	1.55 m 1.75 m	34.8 t	1.03 m 1.24 m	34.2 t	1.55 m 1.77 m
23	17.7 q	0.84 s	17.7 q	0.83 s	23.8 q	1.01 s	24.6 q	0.90 s
24	19.9 q	0.82	24.0 q	0.91 s	19.4 q	1.05 s	20.0 q	0.92 s
25	15.0 q	0.97 s	15.5 q	0.92 s	16.1 q	0.85 s	16.2 q	1.02 s
26	17.8 q	0.96 s	17.8 q	0.83 s	17.5 q	0.92 s	17.9 q	0.86 s
27	26.5 q	1.22 s	26.4 q	1.19 s	24.7 q	1.10 s	26.1 q	1.22 s
28	181.8 s		181.9 s		nd		181.8 s
29	33.5 q	0.94 s	33.6 q	0.95 s	31.0 q	0.85 s	33.2 q	0.95 s
30	24.0 q	0.97 s	24.0 q	0.95 s	23.8 q	0.92 s	24.0 q	0.98 s
1′	38.0 t	1.47 m 1.78 m	40.5 t	1.42 m 1.84 m	34.8 t	1.93 m 2.29 m	37.8 t	1.62 m 1.92 m
2′	70.3 d	4.04 d quint. (1.8, 5.4)	69.6 d	3.94 m	70.8 d	4.42 quint. (5.3)	70.3 d	3.92 quint. (5.7)
3′	67.8 t	3.49 dd (5.7, 10.6) 3.44 dd (5.6, 10.6)	68.6 t	3.48 dd (5.1, 10.9) 3.44 dd (6.4, 10.8)	68.2 t	3.93 dd (5.8, 10.6) 3.83 dd (5.11, 10.7)	68.6 t	3.49 dd (11.7, 6.8) 3.58 dd (11.6, 6.8)

¹ Data collected in MeOH-d₄ for compounds 5, 6, and 8, in Py-d₅ for 7. * Data in parentheses are the values obtained for compound 7 in MeOH-d₄, where it is sparingly soluble. Hence, the complete characterization of 7 was made in Py and a decoupled ¹³C NMR spectrum was registered in methanol in order to compare the signals necessary for the stereochemical analysis.