Table 1.
Selected 1H and 13C NMR signals for compound 2 dissolved in CDCl3 [ppm]. Ni, Pd, and Pt complexes show similar chemical shifts compared to the PtDMSO complex for signals 1–4 [18]. Chemical shifts differ from those observed for Ru and Os compounds [50].
| No. * | Signal | L21 | Ni2 | Pd2 | Pt2 | Ptdmso22 | Ru21 | Os22 |
|---|---|---|---|---|---|---|---|---|
| 1 | =C-H | 6.97 | 7.16 | 7.16 | 7.14 | 7.35 | 6.64 | 6.87 |
| 2 | -C=S | 217.3 | 181.4 | 180.9 | 185.9 | 186.7 | ||
| 3 | =C-H | 112.9 | 115.1 | 113.0 | 112.5 | 112.9 | 113.4 | 112.7 |
| 4 | -C-O- | 169.1 | 178.1 | 178.1 | 174.2 | 179.0 | 174.9 |