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. 2022 Jun 15;23(12):6669. doi: 10.3390/ijms23126669

Table 1.

Selected 1H and 13C NMR signals for compound 2 dissolved in CDCl3 [ppm]. Ni, Pd, and Pt complexes show similar chemical shifts compared to the PtDMSO complex for signals 1–4 [18]. Chemical shifts differ from those observed for Ru and Os compounds [50].

No. * Signal L21 Ni2 Pd2 Pt2 Ptdmso22 Ru21 Os22
1 =C-H 6.97 7.16 7.16 7.14 7.35 6.64 6.87
2 -C=S 217.3 181.4 180.9 185.9 186.7
3 =C-H 112.9 115.1 113.0 112.5 112.9 113.4 112.7
4 -C-O- 169.1 178.1 178.1 174.2 179.0 174.9

* The atoms responsible for signals 1–4 are depicted in Scheme 1. 1, 2 Signals/values reproduced from [18] or [50] with permission of the Royal Society of Chemistry and from the authors, respectively.