Table 2.
Specific bond angles [°] and bond lengths [Å] for nickel(II) and palladium(II) complexes Ni1-Ni6 and Pd1. Additional data are shown in Table S1.
| Ni1 | Ni3 | Ni4 | Ni6 | Pd1 | |
|---|---|---|---|---|---|
| O(1)-M(1) | 1.8466 (17) | 1.8492 (12) | 1.8695 (17) | 1.8720 (16) | 2.023 (4) |
| O(3)-M(1) | 1.8584 (17) | 1.8512 (12) | 1.8668 (18) | 1.8827 (15) | 2.049 (4) |
| S(1)-M(1) | 2.1429 (7) | 2.1434 (4) | 2.1309 (7) | 2.1426 (6) | 2.2307 (16) |
| S(3)-M(1) | 2.1426 (7) | 2.1406 (5) | 2.1396 (7) | 2.1510 (6) | 2.2348 (16) |
| O(1)-C(3) | 1.258 (3) | 1.270 (2) | 1.277 (3) | 1.269 (3) | 1.271 (7) |
| O(3)-C(14) | 1.264 (3) | 1.278 (2) | 1.279 (3) | 1.268 (3) | 1.254 (7) |
| C(1)-S(1) | 1.698 (2) | 1.7075 (18) | 1.708 (3) | 1.711 (2) | 1.703 (6) |
| C(12)-S(3) | 1.696 (2) | 1.7085 (18) | 1.704 (3) | 1.720 (2) | 1.707 (6) |
| O(1)-M(1)-S(1) | 96.42 (6) | 95.47 (4) | 95.22 (6) | 96.44 (5) | 96.78 (13) |
| O(3)-M(1)-S(3) | 97.07 (5) | 95.76 (4) | 95.96 (6) | 95.37 (5) | 94.93 (13) |
| O(1)-M(1)-S(3) | 176.48 (6) | 176.99 (5) | 177.73 (6) | 177.53 (5) | 176.20 (13) |
| S(1)-M(1)-O(3) | 175.71 (6) | 176.90 (4) | 177.55 (7) | 179.16 (6) | 179.22 (13) |
| O(1)-M(1)-O(3) | 80.14 (7) | 81.43 (5) | 84.06 (8) | 83.38 (7) | 83.26 (17) |
| S(1)-M(1)-S(3) | 86.46 (3) | 87.334 (17) | 84.86 (3) | 84.84 (2) | 85.08 (6) |