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(a) Comparison of Nyquist plots of Li/AlN-LLZTO-AlN/Li and Li/LLZTO/Li at 30 °C; (b) DFT calculations of the interface formation energies for Li/LLZTO and AlN/LLZTO; (c) voltage profiles and details for the symmetric (Li/AlN-LLZTO-AlN/Li) cell for current densities of 0.01 mA cm−2 with 0.005 mAh cm−2.
