TABLE 2.

Chemical composition of principal compounds in Water fractions.

Fraction 1.50:50 (Hexane: Acetone)
Compound	Retention time (min)	M-H	M-H formula	Compound CID	References
Psoralen	19.26	187.0968	C11H6O3	6,199	Wu et al. (2010)
Fraction 2.100% Acetone
Psoralen	19.26	187.0959	C11H6O3	6,199	Wu et al. (2010)
Fraction 2. 100% Acetone
Compound	Retention time (min)	M-H	M-H formula	Compound CID	References
Baccatin III	21.16	603.2467	C31H38O11	65,366	Lee et al. (2014)
Limonin-17-beta-D-glucoside	24.08	649.2479	C32H42O14	24,820,753	Mandadi et al. (2007); Jayaprakasha et al. (2010); Brito et al. (2014)
Vanillic acid 4-Beta-D-Glucoside	24.38	329.2315	C14H18O9	14,132,336	Gong et al. (2019); Navarro et al. (2019)
Fraction 3.50:50 (Acetone: Methanol)
Compound	Retention time (min)	M-H	M-H formula	Compound CID	References
Eriodictyol 7-O-glucoside	13.24	449.1078	C21H21O11	13,254,473	Areias et al. (2001); Hu et al. (2012)
Psoralen	19.28	187.0952	C11H6O3	6,199	Wu et al. (2010)
Cyanidin 3-O-(6′′ acetyl) glucoside	22.84	491.2101	C23H23O12	—	Brito et al. (2014); Sorrenti et al. (2015)
Scillirubroside/scilliphaeosidin-glucoside	22.84	607.2842	C28H31O15	—	Knittel et al. (2014)
Glucoscilliphaeoside	24.13	707.3246	C36H52O14	—	Kakouri et al. (2019)
6β-Acetoxyscillarenin3-Oβ-D-glucoside (1→4)-α-l-rhamnoside		753.3319	C38H54O15	—	Kakouri et al. (2019)
Chlorogenic acid		355.2257	C16H18O9	1,794,427	Brito et al. (2014)
Fraction 4.70:10:20 (Butanol: Acetic acid: Water)
Compound	Retention time (min)	M-H	M-H formula	Compound CID	References
Psoralen	19.26	187.0934	C11H6O3	6,199	Wu et al. (2010)