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Structural factors influence building block polymerization and breakdown. (A) Time-dependent comparison of building block conversion to depsipeptides between gA and gβA, which can in principle form six- and seven-atom rings upon dehydration, respectively. Dashed lines were added to guide the eye. Bars: SD; n = 2. (B) Standards (gA)2 and (PA)AgA subject to pH 6, 65 °C aqueous incubation. (C) Structures of molecules used in panel B depicting depolymerization routes.
