Table 1. Kinetic Depolymerization Data for (gA)₂ and (PA)AgA for a Range of Conditions^a.

	(gA)2t1/2 (h)							(PA)AgAt1/2 (h)
(°C)	pH: 2	3	4	5	6	7	8	2	3	4	5	6	7	8
25	674	647	146	43.2	2.78	0.63	0.18	1394	2528	1655	1027	806	88.6	45.0
37	308	298	62.6	12.6	1.34	0.12	0.02	758	1300	826	583	432	51.9	23.9
50	76.8	53.5	26.1	2.91	0.76	0.03	0.01	175	232	281	157	83.2	14.1	3.43
65	34.4	27.9	5.63	0.82	0.17	0.01	0.01	93.3	90.6	94.0	49.8	29.4	4.63	0.88

	(gA)2 depolymerization, (ksc + kbb) (h–1)							(PA)AgA depolymerization, ksc (h–1)*10–3
25	0.001	0.001	0.005	0.016	0.249	1.11	3.96	0.497	0.27	0.419	0.675	0.86	7.83	15.4
37	0.002	0.002	0.011	0.055	0.516	5.86	31.1	0.914	0.533	0.839	1.19	1.60	13.4	29.0
50	0.009	0.013	0.027	0.238	0.914	22.7	66.4	3.95	2.98	2.47	4.42	8.33	49.2	202
65	0.020	0.025	0.123	0.843	4.21	62.3	100	7.43	7.64	7.38	13.9	23.5	150	792

^aSee Supporting Information for calculations and parameters as well as raw data.