. Author manuscript; available in PMC: 2022 Nov 15.

Published in final edited form as: J Phys Chem B. 2021 Nov 1;125(44):12228–12241. doi: 10.1021/acs.jpcb.1c06370

Table 2.

Parameters calculated from the wobbling-in-a-cone analysis. The errors in this table are propagated from those in Table 1. The details of error estimation are presented in Section 9 of the SI.

	θ_lib (°)	θ_c (°)	θ_tot (°)	τ_c (ps)	D_c (10⁻³ ps⁻¹)	τ_m (ps)	D_m (10⁻³ ps⁻¹)
1^PMe3	19 ± 4	20 ± 3	27 ± 2	3.7 ± 1.1	9.4 ± 3.6	21 ± 2	8.0 ± 0.8
1^PMe2Ph	17 ± 3	18 ± 2	24 ± 2	2.6 ± 0.8	10.9 ± 3.8	37 ± 5	4.5 ± 0.6
1^PMePh2	18 ± 3	12 ± 3	21 ± 2	2.8 ± 2.0	4.4 ± 3.8	59 ± 12	2.8 ± 0.6
Free $N_{3}^{-}$	27 ± 1	45 ± 1	51 ± 1	1.5 ±0.1	97 ± 7	6.4 ± 0.4	26 ± 2