(A) Electrochemical impedance spectroscopy of different modified electrodes in solution containing 0.1 M KCl and 5 mM [Fe(CN)6 ]3–/4–. (B) Differential pulse voltammetry (DPV) of different modified electrodes after enrichment for the same time in phosphate-buffered saline (PBS) solution containing 50 ng/mL rutin. (a) Bare gold electrode (230 Ω, 0.12); (b) PC-modified electrode (400 Ω, 2.02); (c) PC/CoWO4 -modified electrode (880 Ω, 4.03); and (d) CoWO4 -modified electrode (26,000 Ω, 1.32).