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. 2022 Feb 17;9(19):2106076. doi: 10.1002/advs.202106076

Figure 8.

Figure 8

“Breathing” ATRP with enzyme‐induced deoxygenation. Grafting from ATRP initiator‐modified protein (BSA) and DNA with photoATRP under 450 nm irradiation. (A) Semilogarithmic kinetic plot, (B) evolution of M n and M w /M n with conversion, (C) Gel permeation chromatography (GPC) traces of cleaved polymers, and (D) evolution of protein–polymer conjugate particle size over the reaction progress, measured by dynamic light scattering. (E) GPC traces of DNA macroinitiator (DNA‐iBBr) and DNA‐pOEOMA500 conjugates after 30 and 45 min of reaction. Reproduced with permission.[ 69 ] Copyright 2018, American Chemical Society.