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. 2022 May 23;94(26):9316–9326. doi: 10.1021/acs.analchem.2c00754

Table 1. Sets of Parameters Used in the Original and Reoptimized Methodsa.

    solariX XR
scimaX 2XR 1 or 2ω
parameters (unit) original reoptimized original reoptimized
laser focusb % 98 80 93 85
laser shots (#shots) 600 [2; 10] 400 6
laser frequency (Hz) 1000 #shots × 10 1000 60
sweep excitation power (%) 22 [16; 18] 20 18
front & back trap plate (V) 1.5 1.35 3 3.06
analyzer entrance (V) –10 –10 –10 –10
side kick (V) 5 [6; 10] 0.2 3
side kick offset (V) –1.0 –1.5 –1.5 –1.5
time of flight (ms) 1.2 1.2 1.0 0.7c
a

The laser power was adjusted to get the lower power possible when the TIC signal was reaching 5 × 108 cps. Values in brackets show a working range.

b

Small and medium laser focus for solariX XR and scimaX 2XR, respectively.

c

Time of flight set at 0.7 ms for the 2ω acquisition for 16 M data point only.