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. 2022 Jun 22;7(26):22244–22255. doi: 10.1021/acsomega.2c00935

Table 4. Logarithmic Binding Constants (log Ka) for Complexes between Receptors and Diverse Anionsb Obtained by 1H NMR, in CD3CN/DMSO-d6 9:1 (v/v) at 298 Ke.

system log K OAc αc OBz αc HSO4 αc NO3
R1 log K11 3.45 0.54 2.75 1.15 1.66   1.48
  log K 12 2.58   2.21        
  log β 6.03   4.97        
R2 log K 11 3.37 1.00 2.87 1.26 2.90 0.15 1.61
  log K12 2.77   2.37   1.48    
  log β 6.14   5.24   4.38    
R3 log K11 3.48 0.45 d   2.06   1.66
  log K12 2.53            
  log β 6.01            
a

Error less than 10%.

b

Anions were added as their TBA salts.

c

Parameter α is used to quantify the extent of cooperativity and is defined as α = 4K2/K1.28,29

d

Not determined due to precipitation.

e

Deprotonation of receptors was observed with H2PO4, F, and PPi3–.