Table 2A. Protonation Constants of Phytate in Different Media and Ionic Strengthsb.
medium | ionic strength(mol L–1) | log K1a | log K2a | log K3 | log K4 | log K5 | log K6 | log K7 | log K8 | log K9 | log K10 | log K11 | log K12 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
(C2H5)4NI | 0.1 | 16.7 | 14.4 | 12.2 | 9.92 | 7.53 | 6.11 | 3.53 | |||||
(n-C4H9)4NBr | >12 | >12 | >12 | 11.5 | 7.97 | 6.41 | 3.93 | 2.73 | 2 | <1.5 | <1.5 | <1.5 | |
LiCl | 9.71 | 9.46 | 8.63 | 7.6 | 6.27 | 5 | 2.63 | ||||||
NaNO3 | 9.48 | 9.98 | 9.53 | 8.2 | 6.49 | 5.17 | 3.02 | ||||||
NaCl | 9.58 | 9.84 | 9.5 | 8.14 | 6.5 | 5.25 | 2.88 | ||||||
KCl | 10.2 | 9.5 | 9.93 | 8.37 | 6.62 | 5.35 | 2.93 | ||||||
CsCl | 10.4 | 10.3 | 10.1 | 8.62 | 6.53 | 5.16 | 3.18 | ||||||
(CH3)4NCl | 0.15 | 10.8 | 10.5 | 10.3 | 8.79 | 6.9 | 5.72 | 3.1 | 1.9 | 1.9 | |||
NaClO4 | 0.15 | 8.59 | 10.5 | 9.02 | 7.82 | 6.13 | 4.88 | 2.49 | 1.98 | ||||
(C2H5)4NClO4 | 0.17 | >13 | >13 | 12.3 | 9.92 | 7.42 | 6.13 | 3.59 | 2 | 2.4 | 1 | <1 | <1 |
KCl | 0.2 | 9.53 | 9.53 | 9.19 | 7.98 | 6.25 | 5.2 | 3.16 | 2.38 | 2.38 | 1.92 | 1.92 | 1.92 |
(C2H5)4NI | 0.5 | 14.9 | 13.3 | 11.6 | 9.79 | 7.5 | 6.12 | 3.61 | |||||
LiCl | 9.06 | 8.81 | 7.96 | 6.93 | 5.63 | 4.39 | 2.08 | ||||||
NaNO3 | 8.73 | 9.39 | 8.82 | 7.57 | 5.88 | 4.59 | 2.6 | ||||||
NaCl | 8.93 | 9.19 | 8.83 | 7.48 | 5.88 | 4.65 | 2.37 | ||||||
KCl | 9.59 | 8.85 | 9.26 | 7.71 | 6.01 | 4.77 | 2.43 | ||||||
CsCl | 9.79 | 9.54 | 9.51 | 7.93 | 5.78 | 4.51 | 2.49 | ||||||
(C2H5)4NI | 1 | 13.6 | 12.5 | 11.1 | 9.71 | 7.5 | 6.16 | 3.72 | |||||
LiCl | 8.83 | 8.57 | 7.69 | 6.67 | 5.4 | 4.15 | 1.92 | ||||||
NaNO3 | 8.36 | 9.22 | 8.51 | 7.34 | 5.66 | 4.39 | 2.52 | ||||||
NaCl | 8.69 | 8.95 | 8.56 | 7.21 | 5.65 | 4.42 | 2.22 | ||||||
NaClO4 | 8.41 | 9.19 | 8.29 | 7.03 | 5.38 | 4.14 | 1.77 | 1.8 | |||||
KCl | 9.35 | 8.61 | 8.99 | 7.45 | 5.77 | 4.54 | 2.28 | ||||||
CsCl | 9.82 | 9.38 | 9.41 | 7.77 | 5.57 | 4.34 | 2.33 | ||||||
LiCl | 3 | 8.6 | 8.34 | 7.34 | 6.35 | 5.18 | 3.95 | 2 | |||||
NaCl | 8.47 | 8.71 | 8.21 | 6.89 | 5.43 | 4.22 | 2.3 | ||||||
NaClO4 | 8.29 | 8.62 | 8.01 | 6.61 | 5.07 | 3.86 | 1.52 | 1.63 | |||||
KCl | 9.13 | 8.38 | 8.64 | 7.13 | 5.56 | 4.34 | 2.36 | ||||||
NaCl | 5 | 8.5 | 8.74 | 8.12 | 6.83 | 5.47 | 4.27 | 2.63 |
Predicated values in italics.
Adapted from Crea et al.79