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. 2021 Sep 15;29(3):468–489. doi: 10.38212/2224-6614.3368

Supplementary Table 1.

Marker peaks for ten herbs in Jia Wei Xiao Yao San.

Herb [M+H]+ of marker peak Predominant peaks in MS/MS (relative intensity) Possible identity
1. Angelicae Sinensis Radix 191.11 191.11 (100) Butylphthalide
173.10 (78)
163.11 (20)
145.10 (34)
117.07 (25)
91.06 (18)
2. Moutan Radicis Cortex 167.07 167.07 (100) Paeonol
149.06 (64)
121.06 (58)
3. Atractylodis Macrocephalae Rhizoma 217.16 217.16 (100) Atractylon
199.15 (11.3)
161.10 (10)
147.12 (9.3)
133.10 (6)
121.10 (5)
107.10 (4)
95.05 (6)
4. Gardeniae Fructus 151.11 151.11 (100) 2,6,6-Trimethyl-1, 3-Cyclohexadiene-1-Carboxaldehyde
135.12 (20)
123.1 (15)
109.10 (23)
95.1 (24)
93.07 (19)
5. Bupleuri Radix 155.10 139.08 (10) Eucalyptol
137.09 (10)
109.10 (100)
95.08 (29)
93.06 (23.8)
6. Poria 139.11 139.11 (100) 2-Pentylfuran
121.10 (9.3)
97.06 (9.0)
95.08 (9.0)
7. Menthae Herba 153.13 153.13 (100) ① Cyclohexanone, 5-methyl-2-(1-methylethylidene)-② (E)-3 (10)-Caren-4-ol ③ 2-Cyclohexen-1-ol, 1-methyl-4-(1-methylethenyl)-, trans-④ Thujone
135.1 (20)
111.08 (20)
109.11 (30)
107.08 (30)
97.06 (38)
95.07 (20)
93.07 (47)
8. Paeoniae Alba Radix 121.10 121.10 (100) Not identified
91.05 (31.8)
9. Zingiberis Rhizoma 137.13 137.13 (100) Not identified
107.09 (99)
95.09 (98)
10. Glycyrrhizae Preparata Radix 100.07 100.07 (100) Not identified
97.06 (4)