Table 2. Molecular Weights (from SEC) and Glass Transition Temperatures of Poly(PFBA-co-BA) and Azide-Modified Poly(PFBA-co-BA).
| code | Mn (kg/mol) | Mw (kg/mol) | D̵ | Tg (°C) |
|---|---|---|---|---|
| PBA | 80.1 | 156.5 | 2.0 | –44 |
| poly(n-butyl acrylate-co-2,3,4,5,6-pentafluorobenzyl acrylate) [poly(PFBA-co-BA)] | ||||
| PFBA-17 | 36.3 | 239.9 | 6.6 | –29 |
| PFBA-9 | 45.8 | 293.6 | 6.4 | –36 |
| PFBA-5 | 32.6 | 272.5 | 8.4 | –39 |
| PFBA-1 | 88.8 | 346.3 | 3.9 | –43 |
| PFBA-0.5 | 87.7 | 164.0 | 1.9 | –44 |
| PFBA-0.3 | 78.5 | 146.0 | 1.9 | –45 |
| PFBA-0.1 | 94.3 | 181.1 | 1.9 | –46 |
| poly(n-butyl acrylate-co-4-azido-2,3,5,6-pentafluorobenzyl acrylate) [azide-modified poly(PFBA-co-BA)] | ||||
| AZ-17 | 50.4 | 364.8 | 7.2 | –27 |
| AZ-9 | 64.2 | 371.7 | 5.8 | –33 |
| AZ-5 | 43.6 | 338.8 | 7.8 | –39 |
| AZ-1 | 101.3 | 391.0 | 3.9 | –43 |
| AZ-0.5 | 70.8 | 111.9 | 1.6 | –47 |
| AZ-0.3 | 74.9 | 152.8 | 2.0 | –46 |
| AZ-0.1 | 90.2 | 144.3 | 1.6 | –45 |