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. 2022 Jul 1;15(13):4647. doi: 10.3390/ma15134647

Table 2.

Uv-vis bands of the Mn-doped bioactive glass-ceramic as a gel at 120 °C and after treatment at 700 and 1100 °C.

Wavelength (nm) 120 °C Wavelength (nm) 700 °C Wavelength (nm) 1100 °C Assignments
516 6A1g (S) → 4T1g (G) transition of Mn2+ ion in octahedral position [45]
485 486 5Eg5T2g transition of Mn3+ ions in octahedral position [45]
469 473 6A1g (S) → 4T1g (G) transition of Mn2+ ion [46]
305 305 294 Mn3O4 [47]
265 MnO (O2− → Mn2+ charge-transfer transition) [45]