Table 2.
Wavelength (nm) 120 °C | Wavelength (nm) 700 °C | Wavelength (nm) 1100 °C | Assignments |
---|---|---|---|
516 | 6A1g (S) → 4T1g (G) transition of Mn2+ ion in octahedral position [45] | ||
485 | 486 | 5Eg → 5T2g transition of Mn3+ ions in octahedral position [45] | |
469 | 473 | 6A1g (S) → 4T1g (G) transition of Mn2+ ion [46] | |
305 | 305 | 294 | Mn3O4 [47] |
265 | MnO (O2− → Mn2+ charge-transfer transition) [45] |