Table 3.
Raman bands of the Mn-doped bioactive glass-ceramic after treatment at 700 and 1100 °C.
| Frequency (cm−1) 700 °C |
Frequency (cm−1) 1100 °C |
Assignments [48] |
|---|---|---|
| 1044 | W [49] (SiO), F [50] (Eg: νasPO4) | |
| 1023 | W [49] (SiO) | |
| 1012 | W [49] (SiO) | |
| 997 | W [49] (SiO) | |
| 967 | W [49] (SiO), F [50] (E2g, Ag: νsPO4) | |
| 954 | νsPO4 | |
| 890 | W [49] | |
| 777 | combination mode or P-O-P defect band | |
| 666 | Mn2O3 [51,52], Ca-F2 | |
| 633 | 638 | W [49], MnO tetraedric |
| 591 | F [50] (Ag: δPO4) | |
| 582 | 581 | W [49], F [50] (E2g: δPO4), ρSiO |
| 518 | ||
| 511 | W [49] | |
| 431 | 429 | F [50] (E1g: δPO4) |
| 412 | W [49] | |
| 391 | W [49], Mn3+-O in Mn3O4 [51,52] | |
| 371 | W [49] | |
| 337 | W [49], Mn3O4 [51,52] | |
| 325 | W [49], F [50] (Ca-F2) | |
| 308 | F [50] (E2g1 lattice mode, Ca-F) | |
| 299 | W [49], F (Ca-PO4) | |
| 230 | W [49] | |
| 166 | 168 | F [50] (E2g4 lattice mode) |
| 140 | F [50] (Ag2 lattice mode) | |
| 131 | F [50] |