Table 3.
No | RI a | LIT.RI b | Components | Treatments c | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
MAD25 Control |
MAD25 TiO2 |
MAD25 AMF |
MAD25 TiO2 + AMF |
MAD50 Control |
MAD50 TiO2 |
MAD50 AMF |
MAD50 TiO2 + AMF |
MAD75 Control |
MAD75 TiO2 |
MAD75 AMF |
MAD75 TiO2 + AMF |
||||
1 | 843 | 847 | cis-Salvene | 0.36 | 0.47 | 0.39 | 0.46 | 0.48 | 0.44 | 0.56 | 0.52 | 0.54 | 0.44 | 0.50 | 0.44 |
2 | 853 | 858 | trans-Salvene | 0.10 | 0.09 | 0.11 | 0.09 | 0.12 | 0.12 | 0.13 | 0.11 | 0.11 | 0.17 | 0.00 | 0.11 |
3 | 919 | 921 | Tricyclene | 0.15 | 0.14 | 0.14 | 0.12 | 0.13 | 0.12 | 0.15 | 0.13 | 0.14 | 0.12 | 0.14 | 0.13 |
4 | 924 | 924 | α-Thujene | 0.15 | 0.16 | 0.18 | 0.21 | 0.20 | 0.20 | 0.19 | 0.21 | 0.18 | 0.17 | 0.20 | 0.14 |
5 | 930 | 932 | α-Pinene | 2.51 | 3.34 | 3.33 | 3.13 | 3.65 | 3.46 | 3.49 | 3.88 | 3.56 | 2.69 | 3.67 | 3.34 |
6 | 944 | 946 | Camphene | 3.11 | 3.44 | 3.32 | 3.58 | 3.71 | 3.64 | 4.00 | 4.35 | 3.87 | 3.15 | 4.17 | 3.40 |
7 | 972 | 974 | β-Pinene | 1.26 | 1.29 | 1.47 | 1.28 | 1.39 | 1.44 | 1.49 | 1.35 | 1.51 | 1.29 | 1.49 | 1.24 |
8 | 989 | 988 | Myrcene | 0.94 | 0.96 | 1.07 | 0.94 | 0.98 | 0.95 | 1.01 | 1.03 | 1.02 | 0.97 | 0.91 | 0.93 |
9 | 999 | 1000 | n-Decane | 0.13 | 0.12 | 0.14 | 0.14 | 0.12 | 0.12 | 0.12 | 0.12 | 0.12 | 0.13 | 0.12 | 0.13 |
10 | 1014 | 1014 | α-Terpinene | 0.31 | 0.39 | 0.40 | 0.36 | 0.38 | 0.38 | 0.40 | 0.42 | 0.37 | 0.40 | 0.38 | 0.40 |
11 | 1021 | 1022 | ρ-Cymene | 1.44 | 1.41 | 1.50 | 1.35 | 1.55 | 1.35 | 1.52 | 1.40 | 1.59 | 1.37 | 1.61 | 1.44 |
12 | 1028 | 1026 | 1,8-Cineole | 9.17 | 10.49 | 10.37 | 9.89 | 9.25 | 9.87 | 10.57 | 9.56 | 9.98 | 10.71 | 9.91 | 10.30 |
13 | 1055 | 1054 | γ-Terpinene | 0.36 | 0.34 | 0.36 | 0.33 | 0.34 | 0.31 | 0.34 | 0.37 | 0.40 | 0.38 | 0.39 | 0.33 |
14 | 1063 | 1065 | cis-Sabinene hydrate | 0.24 | 0.24 | 0.23 | 0.18 | 0.19 | 0.21 | 0.21 | 0.24 | 0.20 | 0.21 | 0.26 | 0.17 |
15 | 1085 | 1086 | Terpinolene | 0.20 | 0.16 | 0.16 | 0.15 | 0.21 | 0.16 | 0.17 | 0.17 | 0.20 | 0.17 | 0.19 | 0.14 |
16 | 1096 | 1098 | trans-Sabinene hydrate | 0.66 | 0.44 | 0.41 | 0.45 | 0.45 | 0.41 | 0.38 | 0.23 | 0.41 | 0.50 | 0.41 | 0.42 |
17 | 1105 | 1101 | cis-Thujone | 30.73 | 33.63 | 34.70 | 33.89 | 31.41 | 33.55 | 33.37 | 35.84 | 33.01 | 33.99 | 32.32 | 32.08 |
18 | 1113 | 1112 | trans-Thujone | 4.59 | 4.97 | 4.94 | 5.30 | 5.04 | 5.53 | 4.91 | 5.68 | 4.97 | 5.52 | 4.87 | 5.07 |
19 | 1140 | 1141 | Camphor | 17.48 | 17.19 | 14.58 | 16.88 | 17.02 | 16.02 | 17.95 | 15.54 | 15.77 | 15.07 | 18.36 | 18.61 |
20 | 1146 | 1147 | neo-iso-3-Thujanol | 0.84 | 0.51 | 0.46 | 0.57 | 0.57 | 0.52 | 0.50 | 0.47 | 0.55 | 0.59 | 0.31 | 0.53 |
21 | 1155 | 1158 | trans-Pinocamphone | 0.12 | 0.12 | 0.05 | 0.11 | 0.13 | 0.06 | 0.12 | 0.06 | 0.10 | 0.15 | 0.05 | 0.12 |
22 | 1161 | 1165 | Borneol | 3.64 | 2.16 | 2.06 | 3.23 | 2.88 | 2.67 | 2.44 | 1.94 | 3.12 | 2.83 | 3.17 | 2.56 |
23 | 1169 | 1172 | cis-Pinocamphone | 0.60 | 0.32 | 0.35 | 0.36 | 0.34 | 0.37 | 0.36 | 0.34 | 0.35 | 0.36 | 0.38 | 0.34 |
24 | 1173 | 1174 | Terpinen-4-ol | 0.06 | 0.10 | 0.10 | 0.06 | 0.06 | 0.06 | 0.07 | 0.06 | 0.06 | 0.07 | 0.03 | 0.09 |
25 | 1186 | 1186 | α-Terpineol | 0.15 | 0.19 | 0.15 | 0.14 | 0.14 | 0.14 | 0.17 | 0.13 | 0.19 | 0.21 | 0.08 | 0.16 |
26 | 1282 | 1284 | Bornyl acetate | 2.27 | 1.57 | 1.84 | 1.80 | 1.94 | 1.69 | 1.54 | 1.42 | 2.21 | 2.25 | 2.50 | 1.41 |
27 | 1290 | 1289 | trans-Sabinyl acetate | 0.00 | 0.12 | 0.08 | 0.13 | 0.08 | 0.06 | 0.07 | 0.11 | 0.08 | 0.09 | 0.00 | 0.10 |
28 | 1413 | 1417 | (E)-Caryophyllene | 2.16 | 2.32 | 2.30 | 2.13 | 2.41 | 2.05 | 1.94 | 2.42 | 1.92 | 2.07 | 1.95 | 2.32 |
29 | 1447 | 1452 | α-Humulene | 2.64 | 2.84 | 2.81 | 2.63 | 3.04 | 2.65 | 2.49 | 3.35 | 2.61 | 2.77 | 2.52 | 3.22 |
30 | 1576 | 1582 | Caryophyllene oxide | 0.38 | 0.36 | 0.35 | 0.36 | 0.42 | 0.43 | 0.33 | 0.40 | 0.39 | 0.40 | 0.36 | 0.30 |
31 | 1585 | 1592 | Viridiflorol | 4.19 | 4.10 | 4.20 | 3.37 | 4.11 | 4.37 | 3.16 | 3.76 | 3.69 | 3.87 | 3.73 | 4.02 |
32 | 1602 | 1608 | Humulene epoxide II | 0.61 | 0.64 | 0.75 | 0.75 | 0.79 | 0.77 | 0.60 | 0.68 | 0.75 | 0.74 | 0.64 | 0.68 |
33 | 2051 | 2056 | Manool | 2.82 | 2.18 | 2.86 | 2.65 | 3.04 | 3.01 | 2.16 | 2.42 | 2.78 | 2.53 | 2.68 | 2.34 |
Total identified (%) | 94.37 | 96.8 | 96.16 | 97.02 | 96.57 | 97.13 | 96.91 | 98.71 | 96.75 | 96.38 | 98.30 | 97.01 | |||
Grouped compounds (%) | |||||||||||||||
Monoterpene hydrocarbons | 10.80 | 11.99 | 12.30 | 11.77 | 12.85 | 12.34 | 13.09 | 13.67 | 13.16 | 11.05 | 13.53 | 11.79 | |||
Oxygenated monoterpenes | 68.04 | 70.12 | 68.17 | 70.88 | 67.29 | 69.20 | 70.84 | 69.85 | 68.51 | 70.00 | 69.89 | 70.28 | |||
Sesquiterpene hydrocarbons | 4.80 | 5.16 | 5.11 | 4.76 | 5.45 | 4.70 | 4.43 | 5.77 | 4.53 | 4.84 | 4.47 | 5.54 | |||
Oxygenated sesquiterpenes | 5.18 | 5.10 | 5.30 | 4.48 | 5.32 | 5.57 | 4.09 | 4.84 | 4.83 | 5.01 | 4.73 | 5.00 | |||
Oxygenated diterpenes | 2.82 | 2.18 | 2.86 | 2.65 | 3.04 | 3.01 | 2.16 | 2.42 | 2.78 | 2.53 | 2.68 | 2.34 | |||
Others | 2.73 | 2.25 | 2.42 | 2.48 | 2.62 | 2.31 | 2.30 | 2.16 | 2.94 | 2.95 | 3.00 | 2.06 |
a RI, linear retention indices on DB-5 MS column, experimentally determined using homologue series of n-alkanes. b Relative retention indices taken from Adams. c MAD25, MAD50, and MAD75 indicating non-stressed, moderate, and severe drought stress, respectively. Control: no fertilizer, AMF: arbuscular mycorrhizal fungi, TiO2: titanium dioxide nanoparticle.