Table 3.
Descriptions of isotherm models
Isotherm model | Description |
---|---|
Langmuir [101] | Considers adsorption as a continuous bombardment of molecules onto a surface with their corresponding desorption or evaporation from the surface with no aggregation at the surface |
Freundlich [102] | Not limited to monolayer formation and can be applied to formation of multilayers. Adsorption heat does not need to be uniformly distributed on the heterogeneous surface of the isotherm |
Redlich–Peterson [103] | Can be applied to heterogenous and homogenous systems as it features both Freundlich and Langmuir models |
SIPS or Langmuir–Freundlich (LF) [104] | Combines Langmuir and Freundlich isotherm models to predict the heterogeneity of the system- it localizes the adsorption without adsorbate–adsorbate interaction |
Toth [105] | Is a modified version of Langmuir model described for heterogenous system considering both low and high concentration of adsorbate (assuming most sites having lower energy) |
Temkin [106] | Considers the interaction between the adsorbent and the adsorbate by ignoring the extremely large and low concentration values- it assumes that adsorption heat of all molecules in the layer declines linearly rather than logarithmically |
Dubinin-Radushkevich (DR) [107] | Associates the mechanism of adsorption to the distribution of Gaussian energy onto the heterogeneous surfaces |