Skip to main content
. 2022 Jul 12:1–30. Online ahead of print. doi: 10.1007/s13399-022-03011-0

Table 3.

Descriptions of isotherm models

Isotherm model Description
Langmuir [101] Considers adsorption as a continuous bombardment of molecules onto a surface with their corresponding desorption or evaporation from the surface with no aggregation at the surface
Freundlich [102] Not limited to monolayer formation and can be applied to formation of multilayers. Adsorption heat does not need to be uniformly distributed on the heterogeneous surface of the isotherm
RedlichPeterson [103] Can be applied to heterogenous and homogenous systems as it features both Freundlich and Langmuir models
SIPS or Langmuir–Freundlich (LF) [104] Combines Langmuir and Freundlich isotherm models to predict the heterogeneity of the system- it localizes the adsorption without adsorbate–adsorbate interaction
Toth [105] Is a modified version of Langmuir model described for heterogenous system considering both low and high concentration of adsorbate (assuming most sites having lower energy)
Temkin [106] Considers the interaction between the adsorbent and the adsorbate by ignoring the extremely large and low concentration values- it assumes that adsorption heat of all molecules in the layer declines linearly rather than logarithmically
Dubinin-Radushkevich (DR) [107] Associates the mechanism of adsorption to the distribution of Gaussian energy onto the heterogeneous surfaces