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. 2022 Mar 23;16(4):4989–5035. doi: 10.1021/acsnano.1c01347

Figure 25.

Figure 25

(a) Schematic of radical pair formation in donor–bridge–acceptor species and pulse sequence in a hypothetical out-of-phase electron spin–echo envelope modulation (OOP-ESEEM) electron paramagnetic resonance (EPR) experiment. (b) Calculated OOP-ESEEM signal from opposite enantiomers in a chiral radical pairs showing different phase shifts. Panels (a,b) adapted with permission from ref (329). Copyright 2021 American Chemical Society. (c) Proposed EPR and (d) Nuclear magnetic resonance (NMR) experiments to elucidate the role of chiral linkers in spin-dependent transfer in chiral donor–bridge–acceptor pairs. Panels (c,d) adapted with permission from ref (330). Copyright 2021 American Chemical Society.