Table 2.
Compd. | RT (min) | [M‒H]− or [M+HCOOH]‒ | Formula | MW | Chemcial name | RBA (%) |
---|---|---|---|---|---|---|
1 | 2.889 | 461.1143 | C19H26O13 | 462 | Sibiricose A3 | 0.15 |
2 | 3.303 | 443.1772 | C20H28O11 | 444 | Sibiricaphenone | 0.04 |
3 | 3.409 | 431.1422 | C24H32O7 | 432 | Acortatarinowin E | 0.13 |
4 | 3.824 | 451.1092 | C21H24O11 | 452 | Telephenone B | 0.18 |
5 | 4.053 | 517.1389 | C22H30O14 | 518 | Sibiricose A5 | 0.17 |
6 | 4.246 | 429.1259 | C19H26O11 | 430 | Polygalatenoside B | 0.11 |
7 | 4.44 | 547.1481 | C23H32O15 | 548 | Sibiricose A6 | 0.18 |
8 | 5.435 | 547.1481 | C23H32O15 | 548 | Sibiricose A1 | 0.12 |
9 | 6.229 | 537.1063 | C24H26O14 | 538 | Sibiricaxanthone B | 0.20 |
10 | 6.416 | 567.1163 | C25H28O15 | 568 | Polygalaxanthone III | 0.11 |
11 | 6.425 | 537.1063 | C24H26O14 | 538 | Sibiricaxanthone A | 0.11 |
12 | 6.531 | 607.1685 | C24H34O15 | 608 | Sibiricose A2 | 0.14 |
13 | 6.773 | 567.1163 | C25H28O15 | 568 | Polygalaxanthone VIII | 0.19 |
14 | 6.963 | 567.1163 | C25H28O15 | 568 | Polygalaxanthone XI | 0.18 |
15 | 7.043 | 549.1429 | C26H30O13 | 550 | Telephiose F | 0.22 |
16 | 7.421 | 667.1659 | C30H36O17 | 668 | Tenuifoliside B | 0.12 |
17 | 7.638 | 607.1685 | C24H34O15 | 608 | Dalmaisione D | 0.11 |
18 | 7.676 | 753.1995 | C34H42O19 | 754 | 3′,4-Disinapoylsucrose | 0.05 |
19 | 7.897 | 607.1685 | C24H34O15 | 608 | Glomeratose A | 0.05 |
20 | 8.098 | 521.185 | C24H26O13 | 522 | Tricornoside C | 0.11 |
21 | 8.34 | 521.185 | C24H26O13 | 522 | Tricornoside F | 0.10 |
22 | 8.839 | 753.1995 | C34H42O19 | 754 | 3,6′-Disinapoylsucrose | 0.21 |
23 | 8.996 | 723.1903 | C33H40O18 | 724 | 3′-O-Feruloyl-6-O sinapoylsucrose | 0.16 |
24 | 9.361 | 429.1264 | C19H26O11 | 430 | Polygalatenoside C | 0.00 |
25 | 9.601 | 681.1806 | C31H38O17 | 682 | Tenuifoliside A | 0.18 |
26 | 9.946 | 977.4995 | C47H80O18 | 933 | Notoginsenoside R1 | 0.16 |
27 | 10.115 | 493.2122 | C25H36O7 | 448 | Asarolignan D | 0.12 |
28 | 10.507 | 845.4609 | C42H72O14 | 846 | Ginsenoside Rg1 | 0.12 |
29 | 10.768 | 783.2088 | C42H72O13 | 784 | Ginsenoside Rg2 | 0.10 |
30 | 10.92 | 767.2175 | C35H44O19 | 768 | Tenuifoliside C | 0.17 |
31 | 11.593 | 1307.3448 | C59H72O33 | 1308 | Tenuifoliose I/J | 0.05 |
32 | 11.674 | 1265.5381 | C57H70O32 | 1267 | Tenuifoliose K | 0.07 |
33 | 11.792 | 1337.353 | C60H74O34 | 1338 | Tenuifoliose B | 0.11 |
34 | 12.039 | 1235.529 | C65H88O23 | 1237 | Arillatanoside A | 0.03 |
35 | 12.237 | 1103.4905 | C53H84O24 | 1104 | Polygalaxanthone XXVIII | 0.12 |
36 | 12.242 | 1307.3448 | C59H72O33 | 1308 | Tenuifoliose I/J | 0.02 |
37 | 12.479 | 1337.353 | C60H74O34 | 1338 | Tenuifoliose D | 0.12 |
38 | 12.717 | 1349.3529 | C61H74O34 | 1350 | Tenuifoliose H | 0.09 |
39 | 12.928 | 1379.3626 | C62H76O35 | 1380 | Tenuifoliose A | 0.16 |
40 | 13.119 | 1409.3733 | C63H78O36 | 1410 | Tenuifoliose N | 0.00 |
41 | 13.38 | 1307.3448 | C61H96O30 | 1308 | Polygalasaponin XXXIV | 0.00 |
42 | 13.389 | 845.4609 | C42H72O14 | 846 | Pseudoginsenoside F11 | 0.07 |
43 | 13.675 | 1337.353 | C60H74O34 | 1338 | Senegose L | 0.00 |
44 | 13.845 | 1307.3448 | C61H96O30 | 1308 | Polygalasaponin XXXVII | 0.00 |
45 | 13.93 | 815.4517 | C41H70O13 | 771 | Notoginsenoside R2 | 0.05 |
46 | 14.387 | 1107.56 | C54H92O23 | 1109 | Ginsenoside Rb1 | 0.05 |
47 | 14.586 | 1195.5702 | C56H94O24 | 1151 | Quinquenoside R1 | 0.01 |
48 | 14.594 | 1193.5564 | C57H94O26 | 1195 | Malonyl-ginsenoside Rb1 | 0.01 |
49 | 14.78 | 1077.5495 | C53H90O22 | 1079 | Ginsenoside Rc | 0.04 |
50 | 14.78 | 1123.5539 | C54H92O24 | 1125 | Koryoginsenoside Rg2 | 0.03 |
51 | 14.908 | 955.4588 | C48H76O19 | 956 | Ginsenoside Ro | 0.21 |
52 | 14.994 | 1119.5584 | C55H92O23 | 1121 | Ginsenoside Rs1 | 0.00 |
53 | 14.994 | 1163.5472 | C56H92O25 | 1165 | Ginsenoside mRc | 0.00 |
54 | 15.121 | 1077.5495 | C53H90O23 | 1079 | Ginsenoside Rb2 | 0.03 |
55 | 15.121 | 1123.5539 | C54H92O24 | 1125 | Notoginsenoside A | 0.02 |
56 | 15.308 | 1119.5584 | C55H92O23 | 1121 | Ginsenoside Rs2 | 0.00 |
57 | 15.308 | 1163.5472 | C56H92O25 | 1165 | Ginsenoside mRb3 | 0.00 |
58 | 15.544 | 1617.6449 | C76H114O37 | 1619 | Onjisaponin R | 0.00 |
59 | 15.566 | 1195.5702 | C56H94O24 | 1151 | Yesanchinoside F | 0.00 |
60 | 15.773 | 1455.595 | C70H104O32 | 1457 | Onjisaponin G | 0.00 |
61 | 15.901 | 1761.6844 | C82H122O41 | 1763 | Onjisaponin V | 0.00 |
62 | 16.011 | 1119.5584 | C55H92O23 | 1121 | Pseudoginsenoside F8 | 0.00 |
63 | 16.085 | 1485.606 | C71H106O33 | 1487 | Onjisaponin E | 0.10 |
64 | 16.118 | 1659.6386 | C78H116O38 | 1661 | Polygalasaponin XLV | 0.00 |
65 | 16.237 | 1425.5885 | C69H102O31 | 1427 | E-Senegasaponin B | 0.00 |
66 | 16.329 | 1119.5584 | C55H92O23 | 1121 | Pseudoginsenoside F8 | 0.00 |
67 | 16.334 | 1455.595 | C70H104O32 | 1457 | Senegin II | 0.00 |
68 | 16.343 | 1587.6325 | C75H112O36 | 1589 | Polygalasaponin XXX | 0.03 |
69 | 16.408 | 1703.6772 | C80H120O39 | 1705 | Onjisaponin A | 0.04 |
70 | 16.596 | 1847.7135 | C86H128O43 | 1849 | Onjisaponin L | 0.00 |
71 | 16.598 | 1587.6325 | C75H112O36 | 1589 | Onjisaponin Wg | 0.00 |
72 | 16.667 | 1599.6327 | C76H112O36 | 1601 | Onjisaponin Gg | 0.00 |
73 | 16.687 | 1731.6713 | C81H120O40 | 1733 | Onjisaponin W | 0.07 |
74 | 16.688 | 1631.6568 | C77H116O37 | 1633 | Onjisaponin O | 0.01 |
75 | 16.951 | 1617.643 | C76H114O37 | 1619 | Polygalasaponin XLIV | 0.03 |
76 | 16.995 | 1571.6369 | C75H112O35 | 1573 | Onjisaponin B | 0.01 |
77 | 17.112 | 1455.595 | C70H104O32 | 1457 | Z-Senegin II | 0.00 |
78 | 17.194 | 1541.6315 | C74H110O34 | 1543 | Onjisaponin H | 0.00 |
79 | 17.242 | 1761.6775 | C82H122O41 | 1763 | Onjisaponin Vg | 0.00 |
80 | 17.252 | 1673.6672 | C79H118O38 | 1675 | Polygalasaponin XXXII | 0.04 |
81 | 17.385 | 1469.61 | C71H106O32 | 1471 | Onjisaponin Z | 0.02 |
82 | 17.39 | 1659.6386 | C78H116O38 | 1661 | Polygalasaponin XLVI | 0.00 |
83 | 17.399 | 1685.6665 | C80H118O38 | 1687 | Onjisaponin Ng | 0.00 |
84 | 17.427 | 1425.5885 | C69H102O31 | 1427 | Myrtifolioside C1 | 0.00 |
85 | 17.446 | 1817.7057 | C85H126O42 | 1819 | Onjisaponin J | 0.00 |
86 | 17.493 | 1791.691 | C83H124O42 | 1793 | Onjisaponin T | 0.00 |
87 | 17.677 | 1587.6325 | C75H112O36 | 1589 | Onjisaponin F | 0.01 |
88 | 17.691 | 1455.595 | C70H104O32 | 1457 | Onjisaponin TH | 0.00 |
89 | 17.743 | 1409.5909 | C69H102O30 | 1411 | Onjisaponin Y | 0.00 |
90 | 17.859 | 1425.5885 | C69H102O31 | 1427 | Z-Senegasaponin B | 0.07 |
91 | 17.995 | 1731.6713 | C81H120O40 | 1733 | Onjisaponin Fg | 0.01 |
92 | 18.007 | 1599.6327 | C76H112O36 | 1601 | Onjisaponin K | 0.00 |
93 | 18.391 | 499.3252 | C31H48O5 | 500 | Poricoic acid GM | 0.22 |
94 | 19.404 | 513.3043 | C31H46O6 | 514 | Poricoic acid HM | 0.23 |
95 | 19.681 | 497.3099 | C31H46O5 | 498 | 16α,25-Dihydroxydehydroeburi conic acid | 0.26 |
96 | 21.003 | 483.2946 | C30H44O5 | 484 | 3-Epidehydrotumulosic acid | 0.22 |
97 | 21.048 | 541.3348 | C33H50O6 | 542 | 6-Hydroxydehydropachymic acid | 0.27 |
98 | 21.277 | 483.3306 | C30H44O5 | 484 | Dehydrotumulosic acid | 5.95 |
99 | 21.343 | 497.3099 | C31H46O5 | 498 | Poricoic acid A | 0.32 |
100 | 21.415 | 485.3461 | C31H50O4 | 486 | Tumulosic acid | 6.23 |
101 | 21.474 | 469.316 | C30H46O4 | 470 | 3β,16α-Dihydroxy-lanosta-7,9(11),24-trien-21-oic acid | 0.71 |
102 | 21.714 | 481.3159 | C31H46O4 | 482 | Polyporenic acid C | 2.23 |
103 | 22.317 | 511.3247 | C32H48O5 | 512 | Poricoic acid AM | 0.34 |
104 | 22.357 | 525.3395 | C33H50O5 | 526 | Dehydropachymic acid | 0.69 |
105 | 22.47 | 513.3407 | C31H46O6 | 514 | 3-O-Acetyl-16a-hydroxytrametenolic acid | 0.31 |
107 | 22.585 | 525.3395 | C33H50O5 | 526 | Poricoic acid AE | 0.29 |
108 | 22.731 | 527.3554 | C33H52O5 | 528 | Pachymic acid | 0.26 |
Note: RT, retention time; MW, molecular weight; RBA, relative binding amount.