Table 1. Photophysical Data of HR-DPP Derivativesa.
| ΔEg(optical gap) (eV) |
Φfl (%) |
τfl (ns) |
kr (ns–1) |
|||||
|---|---|---|---|---|---|---|---|---|
| solution | thin film | solution | thin film | solution | thin film | solution | thin-film | |
| HR-TDPP-HEX | 1.88 | 1.72 | 36.14 | 0.18 | 2.87 | ∼0.28 | 0.12 | ∼6.4 × 10–3 |
| HR-TDPP-C20 | 1.89 | 1.76 | 64.65 | 0.28 | 2.95 | ∼0.62 | 0.21 | ∼4.5 × 10–3 |
| HR-PhDPP-HEX | 2.10 | 2.07 | 77.68 | 5.70 | 4.0 | 3.49 | 0.19 | 16.3 × 10–3 |
ϕfl, fluorescence quantum yield; τfl, fluorescence lifetime; and kr = ϕfl/τfl (ns–1). The optical gap of the molecules is calculated from the absorption spectra red edge(λabs). ΔEg = 1240/λabs eV)