Table 2. CO2 Solubility Data in aq (MDEA + 2-MPZ) Solutiona.
| aq (MDEA+ 2-MPZ) |
T = 303.2 K |
T = 313.2 K |
T = 323.2 K |
|||
|---|---|---|---|---|---|---|
| molal (m) | PCO2/kPa | αCO2 | PCO2/kPa | αCO2 | PCO2/kPa | αCO2 |
| 3.509 + 0.509 | 4.3 | 0.189 ± 0.002 | 5.7 | 0 | 6.6 | 0.139 ± 0.001 |
| 9.8 | 0.331 ± 0.002 | 15.2 | 0.335 ± 0.003 | 18.1 | 0.270 ± 0.002 | |
| 21.2 | 0.462 ± 0.003 | 40.3 | 0.459 ± 0.004 | 33.8 | 0.376 ± 0.003 | |
| 41.2 | 0.569 ± 0.004 | 72.7 | 0.546 ± 0.005 | 56.1 | 0.454 ± 0.004 | |
| 65.1 | 0.644 ± 0.005 | 90.5 | 0.605 ± 0.005 | 73.6 | 0.513 ± 0.005 | |
| 98.5 | 0.683 ± 0.006 | 114.3 | 0.642 ± 0.006 | 99.4 | 0.548 ± 0.005 | |
| 119.1 | 0.708 ± 0.007 | 133.7 | 0.671 ± 0.007 | 114.2 | 0.578 ± 0.006 | |
| 143.1 | 0.722 ± 0.007 | 157.8 | 0.761 ± 0.008 | |||
| 197.3 | 0.749 ± 0.009 | 199.3 | 0.775 ± 0.009 | |||
| 203.2 | 0.753 ± 0.009 | |||||
| 3.017 + 1.008 | 2.3 | 0.183 ± 0.001 | 5.0 | 0.155 ± 0.001 | 5.0 | 0.141 ± 0.001 |
| 10.1 | 0.345 ± 0.002 | 11.5 | 0.303 ± 0.002 | 15.1 | 0.300 ± 0.002 | |
| 20.0 | 0.506 ± 0.004 | 27.0 | 0.435 ± 0.003 | 34.5 | 0.422 ± 0.003 | |
| 44.5 | 0.627 ± 0.005 | 57.9 | 0.534 ± 0.004 | 72.0 | 0.494 ± 0.004 | |
| 86.5 | 0.706 ± 0.006 | 77.6 | 0.596 ± 0.005 | 82.9 | 0.554 ± 0.005 | |
| 118.8 | 0.737 ± 0.007 | 99.2 | 0.638 ± 0.006 | 104.0 | 0.596 ± 0.006 | |
| 146.2 | 0.759 ± 0.007 | 116.9 | 0.670 ± 0.006 | 129.6 | 0.624 ± 0.006 | |
| 183.5 | 0.774 ± 0.008 | 157.4 | 0.760 ± 0.008 | 192.9 | 0.672 ± 0.008 | |
| 235.7 | 0.786 ± 0.010 | 200.0 | 0.767 ± 0.009 | |||
| 279.9 | 0.873 ± 0.011 | |||||
| 335.4 | 1.013 ± 0.013 | |||||
| 2.502 + 1.509 | 3.0 | 0.171 ± 0.001 | 3.7 | 0.134 ± 0.001 | 5.5 | 0.119 ± 0.001 |
| 6.8 | 0.319 ± 0.002 | 7.9 | 0.284 ± 0.002 | 13.2 | 0.249 ± 0.002 | |
| 24.3 | 0.443 ± 0.003 | 18.5 | 0.422 ± 0.003 | 26.5 | 0.377 ± 0.003 | |
| 35.9 | 0.553 ± 0.004 | 44.2 | 0.524 ± 0.004 | 50.5 | 0.485 ± 0.004 | |
| 77.6 | 0.617 ± 0.005 | 69.4 | 0.598 ± 0.005 | 75.4 | 0.550 ± 0.005 | |
| 108.9 | 0.651 ± 0.006 | 97.1 | 0.646 ± 0.006 | 104.4 | 0.585 ± 0.006 | |
| 127.6 | 0.669 ± 0.007 | 118.1 | 0.671 ± 0.006 | 126.9 | 0.609 ± 0.006 | |
| 160.3 | 0.679 ± 0.007 | 136.4 | 0.723 ± 0.007 | 157.0 | 0.634 ± 0.007 | |
| 241.1 | 0.706 ± 0.010 | 149.0 | 0.829 ± 0.008 | |||
| 251.2 | 0.797 ± 0.010 | 180.8 | 0.856 ± 0.009 | |||
The standard uncertainties (u) associated with the measured quantity are u (T) = 0.1 K and u (PCO2) = 0.5 kPa. αCO2 is the CO2 loading of the solvent in mol of CO2 per mol of solvent.