Table 1. Average Crystallite Sizes Calculated for 1–8 from the XRD Data Using (eq 1)a.
| no. | sample | average crystallite size (nm) | % decolorization of Congo red after 25 min | optical band gap energy (eV) |
|---|---|---|---|---|
| 1 | Ni-WC | 34 | 86 | 2.77 |
| 2 | Co-WC | 4 | 66 | 2.50 |
| 3 | Ni-MoC | 25 | 94 | 2.00 |
| 4 | Co-MoC | 22 | 72 | 1.83 |
| 5 | NiCo-WC | 7 | 97 | 2.3 |
| 6 | NiCo-MoC | 15 | 72 | 2.34 |
| 7 | NiFe-WC | 22 | 44 | 1.97 |
| 8 | NiFe-MoC | 32 | 41 | 1.66 |
The % decolorization of Congo red after 25 min of photocatalytic reaction time in the presence of the TMC catalyst. The optical band gap energy was determined using the Tauc plots of 1–8.