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. 2022 Jul 1;144(27):12421–12430. doi: 10.1021/jacs.2c04262

Scheme 1. Schematic Representation of the Coumarin Photocleavage Mechanism Highlighting the Contact Ion Pair (CIP) Intermediate.

Scheme 1

Shown is a model coumarin with a model carboxylic acid payload, in which the fused aromatic ring of the coumarin chromophore is abbreviated by a semicircle.