Table 13. Optical, Electrical, and Photovoltaic Properties of Non-Fullerene Acceptors 5-116–5-204.
| NFA | original name | HOMOa (eV) | LUMOa (eV) | Egopt (eV) | donor | D:A ratio | VOC (V) | JSC(mA cm–2) | FF (%) | PCE (%) | μee(cm2 V–1 s–1) | ref. |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 5-116 | H-IDTzR | –5.31b | –3.44 | 1.87 | P3HT | 1:1 | 1.04 | 6.67 | 53 | 3.53 | -/1.8 × 10–6 | (411) |
| 5-117 | P-IDTzR | –5.31b | –3.42 | 1.89 | P3HT | 1:1 | 1.02 | 9.00 | 55 | 5.01 | -/7.1 × 10–6 | (411) |
| 5-118 | DC-IDT2Tz | –5.63 | –4.03b | 1.60 | PTB7-Th | 1:1.5 | 0.82 | 10.8 | 66 | 5.81 | -/5.0 × 10–7 | (412) |
| 5-119 | T-TPT-T-2F | –5.50 | –3.99 | 1.51 | PBT1-C | 1:1 | 0.93 | 17.6 | 67 | 10.7 | 7.7 × 10–4/1.2 × 10–4 | (413) |
| 5-120 | IDTT2F | –5.57 | –4.03 | 1.46 | PBDB-T | 1:1 | 0.81 | 18.5 | 59 | 8.85 | -/3.1 × 10–6 | (414) |
| 5-121 | IDT-T | –5.57 | –4.01 | 1.56 | PBDB-T | 1:1 | 0.95 | 11.2 | 60 | 6.36 | -/8.2 × 10–6 | (415) |
| 5-122 | 3 | –5.47 | –3.67 | 1.69 | J61 | 1:1 | 0.92 | 8.09 | 43 | 3.17 | -/7.5 × 10–4 | (416) |
| 5-123 | 4 | –5.47 | –3.72 | 1.59 | J61 | 1:1 | 0.89 | 9.27 | 50 | 4.06 | -/6.4 × 10–4 | (416) |
| 5-124 | IDTOT2F | –5.54 | –3.94 | 1.44 | PBDB-T | 1:1 | 0.85 | 20.9 | 72 | 12.8 | -/4.0 × 10–5 | (414) |
| 5-125 | IDTO-T-4F | –5.49 | –3.88 | 1.45 | PBDB-T | 1:1.2 | 0.86 | 20.1 | 73 | 12.6 | -/6.4 × 10–5 | (417) |
| 5-126 | IDTO-Se-4F | –5.48 | –3.90 | 1.40 | PBDB-T | 1:1.1 | 0.83 | 18.6 | 69 | 10.7 | -/4.5 × 10–5 | (417) |
| 5-127 | IDT2Se | –5.41 | –3.87 | 1.45 | PBDB-T | 1:1 | 0.89 | 17.5 | 61 | 9.36 | -/4.8 × 10–5 | (418) |
| 5-128 | IDT2Se-4F | –5.51 | –4.00 | 1.39 | PBDB-T | 1:1 | 0.79 | 21.5 | 66 | 11.2 | -/1.6 × 10–4 | (418) |
| 5-129 | IDT2SeC2C4 | –5.30 | –3.91 | 1.44 | PBDB-T | 1:1 | 0.88 | 17.2 | 59 | 8.92 | 1.3 × 10–4/6.5 × 10–5 | (419) |
| 5-130 | IDT2SeC2C4-2F | –5.37 | –3.99 | 1.40 | PBDB-T | 1:1 | 0.81 | 19.2 | 66 | 10.2 | 1.8 × 10–4/1.5 × 10–4 | (419) |
| 5-131 | IDT2SeC2C4-4F | –5.40 | –4.08 | 1.30 | PBDB-T | 1:1 | 0.77 | 22.0 | 62 | 10.6 | 2.1 × 10–4/1.7 × 10–4 | (419) |
| 5-132 | IFIC | –5.11 | –3.53 | 1.58 | HFQx-T | 1:1 | 1.02 | 11.2 | 55 | 6.28 | -/9.9 × 10–5 | (420) |
| 5-133 | IFIC-F | –5.43 | –3.86 | 1.57 | HFQx-T | 1:1 | 0.95 | 12.0 | 51 | 5.87 | -/1.1 × 10–4 | (420) |
| 5-134 | ITMIC | –5.51b | –4.08 | 1.47 | PM6 | 1:1 | 0.88 | 12.6 | 54 | 5.95 | -/1.5 × 10–4 | (421) |
| 5-135 | IEIC | –5.41c | –3.84c | 1.57 | PBDB-T | 1:1 | 1.02 | 15.1 | 48 | 7.30 | -/1.1 × 10–4 | (422) |
| 5-136 | IE-4F | –5.51c | –4.07c | 1.44 | PBDB-T | 1:1 | 0.87 | 21.4 | 58 | 10.8 | -/3.0 × 10–4 | (422) |
| 5-137 | IE-4Cl | –5.54c | –4.11c | 1.43 | PBDB-T | 1:1 | 0.86 | 21.5 | 60 | 11.1 | -/3.7 × 10–4 | (422) |
| 5-138 | A1 | –5.15 | –3.73 | 1.55 | J71 | 1:1 | 0.97 | 5.71 | 30 | 1.63 | 3.5 × 10–5/1.2 × 10–5 | (144) |
| 5-139 | IDT-TN | –5.42 | –4.03 | 1.43 | PBDB-T | 1:1 | 0.97 | 13.2 | 45 | 5.89 | 1.2 × 10–6/6.8 × 10–5 | (423) |
| 5-140 | ERCN | –5.50 | –3.59 | 1.82 | P3HT | 1:1.3 | 0.90 | 5.87 | 50 | 2.64 | -/2.7 × 10–5 | (424) |
| 5-141 | IDTP-P-C | –5.37 | –3.72 | 1.42 | PTB7-Th | 1:1 | 0.79 | 18.8 | 55 | 8.21 | 7.2 × 10–4/8.6 × 10–4 | (425) |
| 5-142 | IDTP-O-C | –5.43 | –3.75 | 1.44 | PTB7-Th | 1:1 | 0.77 | 18.1 | 62 | 8.61 | 1.4 × 10–3/9.5 × 10–4 | (425) |
| 5-143 | IDTCN-C | –5.59 | –3.92 | 1.48 | PBDB-T | 1:1 | 0.84 | 20.3 | 70 | 11.9 | -/9.5 × 10–5 | (426) |
| 5-144 | p-IO1 | –5.46 | –4.13 | 1.34 | PTB7-Th | 1:1.5 | 0.78 | 22.3 | 62 | 10.8 | (427) | |
| 5-145 | o-IO1 | –5.44 | –4.15 | 1.28 | PTB7-Th | 1:1.5 | 0.74 | 26.3 | 67 | 13.1 | (427) | |
| 5-146 | o-IO2 | –5.41 | –4.21 | 1.20 | PTB7-Th | 1:1.5 | 0.68 | 21.8 | 63 | 9.3 | (427) | |
| 5-147 | p-IO2 | –5.44 | –4.19 | 1.24 | PTB7-Th | 1:1.5 | 0.70 | 23.0 | 67 | 10.8 | (427) | |
| IEICO-4F | –5.43d | –4.03d | Si25-H2 | 1:1.5 | 0.70 | 26.9 | 70 | 13.2 | 1.2 × 10–4/9.2 × 10–4 | (428) | ||
| 5-148 | IEICO-4Cl | –5.56 | –4.23 | D18 | 1:1.6 | 0.80 | 3.45 | 49 | 1.42 | (136) | ||
| 5-149 | IOTIC-2F | –5.34 | –4.06 | 1.31 | PTB7-Th | 1:1.5 | 0.82 | 21.9 | 65 | 12.1 | -/2.1 × 10–5 | (181) |
| 5-150 | IEICO | –5.32d | –3.95d | PTB7-Th | 1:1.5 | 0.90 | 12.5 | 59 | 6.7 | -/3.1 × 10–4 | (429) | |
| 5-151 | ORCN | –5.37 | –3.56 | 1.64 | P3HT | 1:1.3 | 0.87 | 11.5 | 62 | 6.40 | -/1.8 × 10–4 | (424) |
| 5-152 | IDTP-P-O | –5.21 | –3.75 | 1.28 | PTB7-Th | 1:1 | 0.73 | 19.1 | 59 | 8.17 | 3.7 × 10–3/2.6 × 10–3 | (425) |
| 5-153 | IDTP-O-O | –5.27 | –3.76 | 1.30 | PTB7-Th | 1:1 | 0.73 | 19.0 | 60 | 8.40 | 6.5 × 10–3/2.9 × 10–3 | (425) |
| 5-154 | IDTCN-O | –5.54 | –3.80 | 1.53 | PBDB-T | 1:1 | 0.91 | 20.0 | 73 | 13.3 | -/7.6 × 10–5 | (426) |
| 5-155 | IDTCN-S | –5.57 | –3.90 | 1.48 | PBDB-T | 1:1 | 0.85 | 19.0 | 66 | 10.6 | -/4.5 × 10–5 | (426) |
| 5-156 | ACS8 | –5.54 | –4.05 | 1.30 | PTB7-Th | 1:2 | 0.75 | 25.3 | 69 | 13.2 | 2.7 × 10–4/2.0 × 10–4 | (430) |
| 5-157 | A134 | –5.54 | –4.05 | PTB7-Th | 1:2 | 0.75 | 16.7 | 61 | 7.6 | (275) | ||
| 5-158 | i-IEICO | –5.31 | –3.68 | 1.60 | J52 | 1:1 | 0.96 | 18.8 | 58 | 10.5 | -/1.1 × 10–4 | (431) |
| 5-159 | i-IEICO-2F | –5.29b | –3.73 | 1.58 | J52 | 1:1 | 0.91 | 20.9 | 68 | 12.9 | -/2.0 × 10–4 | (432) |
| 5-160 | i-IEICO-F3 | –5.34b | –3.74 | 1.59 | J52 | 1:1 | 0.90 | 16.2 | 53 | 7.65 | -/2.8 × 10–5 | (432) |
| 5-161 | i-IEICO-4F | 1.56 | J52 | 1:1 | 0.85 | 22.9 | 68 | 13.2 | -/3.8 × 10–4 | (433) | ||
| 5-162 | i-cc23 | –5.34 | –3.64 | 1.69 | PBDB-T | 1:1 | 1.10 | 11.2 | 59 | 7.34 | -/1.8 × 10–5 | (434) |
| 5-163 | i-cc34 | –5.39 | –3.75 | 1.57 | PBDB-T | 1:1 | 0.96 | 15.7 | 63 | 9.51 | -/1.2 × 10–4 | (434) |
| 5-164 | i-mO-4F | –5.50 | –3.81 | 1.55 | PBDB-T | 1:1 | 0.92 | 21.6 | 71 | 14.0 | -/2.2 × 10–4 | (435) |
| 5-165 | i-mO-4Cl | –5.55 | –3.83 | 1.53 | PBDB-T | 1:1 | 0.87 | 15.1 | 56 | 7.41 | -/5.1 × 10–5 | (435) |
| 5-166 | IDT-OT | –5.11 | –3.46 | PBDB-T | 1:1.5 | 0.93 | 8.27 | 43 | 3.32 | -/1.1 × 10–4 | (436) | |
| 5-167 | IDTS-4F | –5.54 | –3.93 | 1.43 | PM6 | 1:1 | 0.89 | 21.0 | 70 | 12.9 | -/3.1 × 10–4 | (437) |
| 5-168 | IDT2ST-4F | –5.36 | –3.71 | 1.43 | PBDB-T | 1:1 | 0.85 | 19.4 | 69 | 11.4 | -/3.3 × 10–5 | (438) |
| 5-169 | ITOIC | –5.48 | –3.75 | 1.55 | PBDB-T | 1:1 | 1.02 | 15.7 | 55 | 8.87 | 2.5 × 10–5/2.4 × 10–4 | (439) |
| 5-170 | ITOIC-F | –5.52 | –3.82 | 1.50 | PBDB-T | 1:1 | 0.95 | 18.6 | 61 | 10.7 | 6.5 × 10–5/4.9 × 10–4 | (439) |
| 5-171 | ITOIC-2F | –5.57 | –3.87 | 1.45 | PBDB-T | 1:1.5 | 0.90 | 21.0 | 65 | 12.2 | 1.3 × 10–4/6.0 × 10–4 | (439) |
| 5-172 | IDT-EDOT | –5.43 | –3.80 | 1.41 | PBDB-T | 1:1.2 | 0.86 | 21.3 | 62 | 11.3 | -/6.6 × 10–5 | (440) |
| 5-173 | IDT-PDOT | –5.39 | –3.77 | 1.43 | PBDB-T | 1:0.5 | 0.85 | 5.26 | 49 | 2.18 | -/3.0 × 10–6 | (440) |
| 5-174 | IDT-PDOT-C6 | –5.59c | –4.17 | 1.42 | PBDB-T | 1:1 | 0.91 | 19.5 | 62 | 11.1 | -/3.1 × 10–4 | (441) |
| 5-175 | ITCIC | –5.59b | –4.12 | 1.43 | PM6 | 1:1 | 0.86 | 20.5 | 64 | 11.3 | -/4.3 × 10–4 | (421) |
| 5-176 | IDT-3MT | –5.68 | –4.16 | 1.52 | PBDB-T | 1:1 | 0.95 | 14.4 | 61 | 8.40 | -/1.0 × 10–5 | (415) |
| 5-177 | IDT-TiFIC | –5.57 | –4.05 | 1.41 | PBDB-T | 1:1 | 0.86 | 17.0 | 65 | 9.46 | -/2.1 × 10–4 | (442) |
| 5-178 | IDT-ToFIC | –5.55 | –3.86 | 1.50 | PBDB-T | 1:1 | 0.88 | 17.8 | 71 | 11.1 | -/3.9 × 10–4 | (442) |
| 5-179 | ITVT | –5.47 | –3.59 | 1.48 | PBZ | 1:2 | 0.96 | 14.2 | 43 | 5.84 | 1.9 × 10–4/1.4 × 10–4 | (443) |
| 5-180 | A401 | –5.43 | –3.53 | PBDB-T | 1:1 | 0.93 | 13.0 | 62 | 7.54 | -/3.1 × 10–6 | (444) | |
| 5-181 | IDTO-TT-4F | –5.39 | –3.89 | 1.38 | PBDB-T | 1:1.1 | 0.86 | 17.2 | 69 | 10.2 | -/2.2 × 10–5 | (417) |
| 5-182 | IDTC-4Cl | –5.50 | –3.79 | 1.35 | PBDB-T | 1:1 | 0.82 | 19.2 | 60 | 9.50 | 2.8 × 10–4/2.5 × 10–4 | (445) |
| 5-183 | 4TIC | –5.36 | –4.11 | 1.26 | PTB7-Th | 1:1.3 | 0.70 | 14.6 | 49 | 5.26 | -/4.4 × 10–4 | (446) |
| 5-184 | 4T4F | –5.38 | –4.13 | 1.22 | PTB7-Th | 1:1.3 | 0.60 | 17.3 | 60 | 6.58 | -/4.8 × 10–4 | (446) |
| 5-185 | 6TIC | –5.31 | –3.96 | 1.30 | PTB7-Th | 1:1.3 | 0.74 | 19.2 | 54 | 8.13 | -/9.8 × 10–4 | (446) |
| 5-186 | 6T4F | –5.45 | –4.00 | 1.23 | PTB7-Th | 1:1.3 | 0.60 | 24.9 | 69 | 10.7 | -/1.3 × 10–3 | (446) |
| 5-187 | ATT-5 | –5.41 | –3.60 | 1.50 | PBDB-T | 1:1 | 0.93 | 18.9 | 71 | 12.4 | 2.1 × 10–4/2.5 × 10–4 | (447) |
| 5-188 | IFIC-i-2F | –5.42 | –3.91 | 1.34 | PTB7-Th | 1:1.8 | 0.72 | 21.0 | 65 | 9.82 | -/2.3 × 10–4 | (448) |
| 5-189 | IFIC-i-6F | –5.31 | –4.00 | 1.27 | PTB7-Th | 1:1.8 | 0.61 | 22.0 | 70 | 9.43 | -/7.9 × 10–4 | (448) |
| 5-190 | IFIC-i-4F | –5.34 | –3.96 | 1.30 | PTB7-Th | 1:1.8 | 0.65 | 24.9 | 67 | 10.9 | -/5.1 × 10–4 | (448) |
| 5-191 | IFIC-o-4F | –5.36 | –4.01 | 1.27 | PTB7-Th | 1:1.8 | 0.61 | 18.6 | 62 | 7.01 | -/3.4 × 10–5 | (448) |
| 5-192 | ATT-1 | –5.51 | –3.68 | 1.54 | PBDB-T | 1:1 | 0.92 | 16.4 | 60 | 9.00 | 8.6 × 10–5/0.1 × 10–4 | (447) |
| 5-193 | ATT-4 | –5.41 | –3.62 | 1.49 | PBDB-T | 1:1 | 0.93 | 17.3 | 70 | 11.2 | 3.7 × 10–4/1.0 × 10–4 | (447) |
| 5-194 | ATT-6 | –5.48 | –3.66 | 1.53 | PBDB-T | 1:1 | 0.96 | 14.7 | 59 | 8.39 | -/2.4 × 10–5 | (449) |
| 5-195 | ATT-7 | –5.45 | –3.61 | 1.54 | PBDB-T | 1:1 | 0.97 | 16.0 | 67 | 10.3 | -/5.4 × 10–5 | (449) |
| 5-196 | ATT-8 | –5.46 | –3.71 | 1.55 | PBDB-T | 1:1 | 0.80 | 13.9 | 65 | 7.31 | -/1.9 × 10–5 | (450) |
| 5-197 | TPD3 | –5.65 | –3.79 | 1.71 | J52-Cl | 1:1.5 | 0.96 | 12.7 | 62 | 7.58 | -/1.1 × 10–6 | (451) |
| 5-198 | TPD8 | –5.60 | –4.10b | 1.46 | PTQ10 | 1:1.5 | 0.91 | 18.2 | 63 | 10.4 | -/1.3 × 10–4 | (452) |
| 5-199 | IDBTC | –5.25 | –3.54 | 1.57 | P3HT | 0.73 | 7.7 | 45 | 2.5 | (453) | ||
| 5-200 | IDBTCF | –5.27 | –3.55 | 1.56 | P3HT | 0.75 | 8.93 | 48 | 3.22 | (453) | ||
| 5-201 | IDTBF | –5.64 | –3.80 | 1.58 | PM6 | 1:1 | 0.94 | 17.0 | 65 | 10.4 | -/2.5 × 10–4 | (454) |
| 5-202 | 2FIFIC | –5.45 | –3.97 | 1.38 | PM6 | 1:1.4 | 0.80 | 22.4 | 62 | 11.3 | -/8.0 × 10–4 | (455) |
| 5-203 | ICIF2F | –5.45 | –4.02 | 1.36 | PM6 | 1:1.4 | 0.79 | 19.3 | 61 | 9.60 | -/5.7 × 10–4 | (455) |
| 5-204 | IDST-4F | –5.59 | –4.01 | 1.41 | PM6 | 1:1.25 | 0.82 | 24.9 | 70 | 14.3 | -/4.3 × 10–4 | (456) |
a
Obtained from the oxidation/reduction potential of the CV measurement if not otherwise stated.
b
HOMO/LUMO energy levels obtained from the LUMO/HOMO levels determined by CV and the optical band gap.
c
Obtained via ultraviolet photoelectron spectroscopy (UPS).
d
Method not defined.
e
Determined via the SCLC technique from the neat acceptor/donor:acceptor blend films if not otherwise stated.