Table 1.
Anodic peak potentials for 1‐6 † and rate constants (k q) for the fluorescence quenching of 1[3‐CN‐NMQ+]* by 1‐5. ‡
| Sulfoxide | (V) vs SCE | k q (× 1010 m −1 s−1) |
|---|---|---|
| 1 | 2.04 | 1.35 |
| 2 | 1.89 | 1.69 |
| 3 | 1.85 | 1.32 |
| 4 | 1.77 | 0.52 |
| 5 | 1.84 | 0.73 |
| 6 | 1.80 |
In MeCN at 25 °C using an Ag/AgCl (KCl 3 m) as the reference electrode.
In MeCN at 25 °C.